| 105101-72-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 105101-72-2
• 化学式: Au*C₁₉H₁₇P*Cl
• 分子量: 508.737
• InChiKey: JZONVFXUIVUITB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  4.17
• 重原子数：
  22.0
• 可旋转键数：
  5.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  、 4,5-bis(benzoylthio)-1,3-dithiole-2-selenone 在 sodium 作用下， 以 甲醇 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  Gold complexes with 2-selenoxo-1,3-dithiole-4,5-dithiolato

  摘要：

  The reaction of Na(2)dmise (dmise = 2-selenoxo-1,3-dithioIe-4,5-dithielate) with [AuClL] in 1:2 molar ratio affords [Au-2(dmise)L-2] (L = PR3 or CH2PPh3) but in 1:1 ratio in the presence of (NBu4) Pr gives (NBu4)[Au(dmise)L]. The PPh2Me dinuclear derivative further reacts with [Au(OClO3)(PPh2Me)] to give [Au-3(dmise)(PPh2Me3)(3)]ClO4. The reaction with [Au-2(P-P)Cl-2] renders [Au-2(P-P)(dmise)](n) with different nuclearity depending on the diphosphine used (P-P = dppe, n = 1; dppm, n = 2). Anionic derivatives (PPN)(2)[Au-2(dmise)(C6F5)(2)] and (PPN)[Au(dmise)(2)] are obtained by reaction with the corresponding haloanionic gold complexes. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00302-1

文献信息

• Synthesis of Heteropolynuclear Complexes Using New Tin(IV) Dimers. X-ray Structure of [AuSnCl(<b><i>^t</i></b>Bu)₂(SC₆H₄)(PPh₃)]
  作者：Eduardo J. Fernández、Michael B. Hursthouse、Mariano Laguna、Raquel Terroba

  DOI：10.1021/om970326p

  日期：1997.12.1

  [SnR2(SC6H4)}2] (R = Me, tBu, Ph) (1a−c). The reaction of these dimer derivatives with various [AuClL] breaks the tin-sulfur bonds, affording the heterobimetallic complexes [AuSnClR2(SC6H4)L] (L = PPh3, AsPh3, CH2PPh3) (2−4). The synthesis of [AuSnClMe2(SC6H4)}2] (5) is carried out in a similar way. The lithiated product Li2(SC6H4) can react with [AuCl(PPh3)], giving [Au2(SC6H4)(PPh3)2] (6). The molecular

  Li 2（SC 6 H 4）与[SnR 2 Cl 2 ]反应，得到双核衍生物[SnR 2（SC 6 H 4）} 2 ]（R = Me，tBu，Ph）（1a-c）。这些二聚体衍生物与各种[AuClL]的反应打破了锡-硫键，提供了异双金属配合物[AuSnClR 2（SC 6 H 4）L]（L = PPh 3，AsPh 3，CH 2 PPh 3）（2- 4）。[Au SnClMe 2（SC 6 H 4）} 2 ]（5）的合成以类似的方式进行。锂化产物Li 2（SC 6 H 4）可与[AuCl（PPh 3）]反应，得到[Au 2（SC6 H 4）（PPh 3）2 ]（6）。配合物[AuSnCl（tBu）2（SC 6 H 4）（PPh 3）]（2b）已通过X射线衍射建立，显示出四面体锡中心和由“ CS”双齿配体桥接的线性金（I）原子。
• Bi-, tetra-, and poly-nuclear complexes of gold(<scp>I</scp>) and silver(<scp>I</scp>) with bis(diphenylphosphino)-methanide or -amide acting as six-electron donors
  作者：Rafael Usón、Antonio Laguna、Mariano Laguna、Ma. Concepción Gimeno

  DOI：10.1039/dt9890001883

  日期：——

  [AuCl(CH2PPh3)] or [Ag(CH2PPh3)2]ClO4 with bis(diphenylphosphino)amine, bis(diphenylphosphino)methane, or bis(diphenylthiophosphoryl)amine leads to neutral complexes [X(Ph2PAuPPh2)2X][X = CH (1) or N (2)], [NPh2P(S)Au(S)PPh2}2N](3)[N(Ph2PAgPPh2)2N](4), or [NPh2P(S)Ag(S)PPh2}2N](5). Complexes (1), (2), and (4) react further with gold or silver complexes giving tetranuclear ring-system derivatives

  [AuCl（CH 2 PPh 3）]或[Ag（CH 2 PPh 3）2 ] ClO 4与双（二苯基膦基）胺，双（二苯基膦基）甲烷或双（二苯基硫代磷酰基）胺的反应生成中性络合物[X （Ph 2 PAuPPh 2）2 X] [X = CH（1）或N（2）]，[N Ph 2 P（S）Au（S）PPh 2 } 2 N]（3）[N（Ph 2 PAgPPh 2）2 N]（4）或[N Ph 2 P（S）Ag（S）PPh 2 }2 N]（ 5）。配合物（ 1），（ 2）和（ 4）进一步与金或银配合物反应，得到四核环系统衍生物，其中酰胺或甲酰胺基配体充当六电子供体配体。
• Unprecedented co-ordination mode of the tetrathio-molybdate or -tungstate anions in heterometallic gold complexes. Crystal structures of [MoS4(AuAsPh3)2] and [WS4(AuCH2PPh3)2]·CH 2Cl2
  作者：Fernando Canales、M. Concepción Gimeno、Peter G. Jones、Antonio Laguna

  DOI：10.1039/a603312a

  日期：——

  Treatment of the tetrathiometalates [NH 4 ] 2 [MS 4 ] (M = Mo or W) with [AuCl(AsPh 3 )] (molar ratio 1∶2) gave the trinuclear species [MS 4 (AuAsPh 3 ) 2 ] (M = Mo 1 or W 2). Stepwise substitution of the arsine ligand afforded the complexes [MS 4 (AuAsPh 3 )(AuPPh 3 )] (M = Mo 3 or W 4) or [MS 4 (AuPPh 3 )(AuPPh 2 Me)] (M = Mo 5 or W 6). The reaction with gold(I) complexes [AuCl(ylide)] follows a different pathway depending on the ylide ligand; with the less sterically demanding CH 2 PPh 2 Me the species [MS 4 (AuCH 2 PPh 2 Me) 2 ] (M = Mo 7 or W 8) with three-co-ordinate gold were formed, but the ylide CH 2 PPh 3 led to [MS 4 (AuCH 2 PPh 3 ) 2 ] (M = Mo 9 or W 10) with one three- and one two-co-ordinate gold centre. The crystal structures of complexes 1 and 10 were determined by X-ray diffraction.

  四硫金属盐 [NH₄]₂[MS₄] (M = Mo或W) 与 [AuCl(AsPh₃)] 以摩尔比1:2反应，得到三核物种 [MS₄(AuAsPh₃)₂] (M = Mo 1或W 2)。逐步取代砷烯配体得到的复合物为 [MS₄(AuAsPh₃)(AuPPh₃)] (M = Mo 3或W 4) 或 [MS₄(AuPPh₃)(AuPPh₂Me)] (M = Mo 5或W 6)。与金(I)配合物 [AuCl(ylide)] 的反应则依据ylide配体的不同而有不同途径；与相对空间占用较小的 CH₂PPh₂Me 反应时，形成了具有三配位金的物种 [MS₄(AuCH₂PPh₂Me)₂] (M = Mo 7或W 8)，而ylide CH₂PPh₃ 则导致生成 [MS₄(AuCH₂PPh₃)₂] (M = Mo 9或W 10)，其中包含一个三配位和一个双配位金中心。复合物1和10的晶体结构通过X射线衍射确定。
• Di- and tetra-nuclear complexes with bis(diphenylphosphino)amide and bis(diphenylphosphino)methanide as bi- and tri-dentate ligands. X-Ray structures of [(Ph₃P)(O₃ClO)AgN(Ph₂PAuPPh₂)₂NAg(OClO₃)(PPh₃)] and [(C₆F₅)AuCH(Ph₂PAuPPh₂)₂ChAu(C₆F₅)]
  作者：Rafael Usón、Antonio Laguna、Mariano Laguna、Ma Concepción Gimeno、Peter G. Jones、Christa Fittschen、George M. Sheldrick

  DOI：10.1039/c39860000509

  日期：——

  Deprotonation of bis(diphenylphosphino)amine or bis(diphenylphosphino)methane with [AuCl(CH2PR3)] leads to neutral complexes [X(Ph2PAuPPh2)2X](X = N or CH) that react further with [Au(C6F5)(tht)](tht = tetrahydrothiophene) or [Ag(OClO3)(PPh3)], giving neutral tetranuclear derivatives, ring systems in which the amido or methanido ligands are tridentate (confirmed by X-ray structures of two products).

  双(二苯基膦)胺或双(二苯基膦)甲烷与[AuCl(CH2PR3)]发生去质子化反应，生成中性配合物[X(Ph2PAuPPh2)2X]（X = N 或 CH），并与[Au(C6F5)(tht)]（tht = 四氢噻吩）或[Ag(OClO3)(PPh3)]进一步反应、产生中性四核衍生物，即氨基或甲酰氨基配体为三位一体的环系统（两种产物的 X 射线结构证实了这一点）。
• Synthesis and X-ray crystal structure of salts of the bis(1,2-dimethyl-dicarbadodecarborane)aurate(III) anion
  作者：M.Concepción Gimeno、Antonio Laguna、Mariano Laguna、Peter G. Jones

  DOI：10.1016/s0020-1693(00)80397-7

  日期：1991.11

  Me[AuBr 2 ] or AuX(ylide)) or gold(III) complexes [AuCl 3 (SC 4 H 8 ] gives Q[Au(1,2-Me 2 C 2 B 9 H 9 ) 2 ] (Q = PPh 3 Me, [Au(ylide) 2 ] or N(PPh 3 ) 2 ). The structure of [N(PPh 3 ) 2 ][Au(1,2-Me 2 C 2 B 9 H 9 ) 2 ] has been established by X-ray crystallography. It crystallizes in Pnma with a = 25.792(8), b = 12.810(3), c = 10.994(3) A (at −95 °C), Z = 4, R = 0.027, R w = 0.029. The gold atom is coordinated

  摘要Tl 2（1,2-Me 2 C 2 B 9 H 9）与金（I）（PPh 3 Me [AuBr 2]或AuX（内酯））或金（III）络合物[AuCl 3（SC） 4 H 8]给出Q [Au（1,2-Me 2 C 2 B 9 H 9）2]（Q = PPh 3 Me，[Au（ylide）2]或N（PPh 3）2）。 [N（PPh 3）2] [Au（1,2-Me 2 C 2 B 9 H 9）2]通过X射线晶体学确定，其在Pnma中结晶，a = 25.792（8），b = 12.810 （3），c = 10.994（3）A（在-95°C时），Z = 4，R = 0.027，R w = 0.029。金原子由每个C2B3面的硼原子配位，AuB = 2.193–2.277安。