tert-Butyl-[(Z)-1-ethyl-5-(2,5,5-trimethyl-[1,3]dioxan-2-yl)-pent-2-enyloxy]-dimethyl-silane | 177190-89-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tert-Butyl-[(Z)-1-ethyl-5-(2,5,5-trimethyl-[1,3]dioxan-2-yl)-pent-2-enyloxy]-dimethyl-silane
• CAS: 177190-89-5
• 化学式: C₂₀H₄₀O₃Si
• 分子量: 356.621
• InChiKey: URDWEDMEGWWOGC-QBFSEMIESA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.91
• 重原子数：
  24.0
• 可旋转键数：
  7.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.9
• 拓扑面积：
  27.69
• 氢给体数：
  0.0
• 氢受体数：
  3.0

反应信息

• 作为反应物：
  描述：

  tert-Butyl-[(Z)-1-ethyl-5-(2,5,5-trimethyl-[1,3]dioxan-2-yl)-pent-2-enyloxy]-dimethyl-silane 在 间氯过氧苯甲酸 作用下， 以 二氯甲烷 为溶剂， 反应 18.0h， 生成 tert-Butyl-dimethyl-(1-{3-[2-(2,5,5-trimethyl-[1,3]dioxan-2-yl)-ethyl]-oxiranyl}-propoxy)-silane
  参考文献：
  名称：

  Identification and synthesis of new bicyclic acetals from the mountain pine beetle, Dendroctonus ponderosae hopkins (Col.: Scol.)

  摘要：

  Head-space volatiles obtained from male mountain pine beetles, Dendroctonus ponderosae, were analyzed by coupled CC-MS and chiral gas chromatography. 5-Ethyl-7-methyl-6,8-dioxabicyclo[3.2.1] (6) was found as a new naturally occurring isomer of brevicomin (1). In addition, several stereoisomers of 7-ethyl-5-methyl-6,8-dioxabicyclo[3.2.1] (11) and 1-(5-methyl-6,8-dioxabicyclo[3.2.1]octyl)ethanol (12) could be identified. Relative and absolute configurations of the compounds were determined by unambiguous syntheses, which are described. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0968-0896(96)00013-2
• 作为产物：
  描述：

  2-(2-溴乙基)-2,5,5-三甲基-1,3-二噁烷 在 Lindlar's catalyst 咪唑 、 喹啉 、 正丁基锂 、 氢气 作用下， 以 正庚烷 、 N,N-二甲基甲酰胺 为溶剂， 20.0 ℃ 、101.33 kPa 条件下， 反应 6.0h， 生成 tert-Butyl-[(Z)-1-ethyl-5-(2,5,5-trimethyl-[1,3]dioxan-2-yl)-pent-2-enyloxy]-dimethyl-silane
  参考文献：
  名称：

  Identification and synthesis of new bicyclic acetals from the mountain pine beetle, Dendroctonus ponderosae hopkins (Col.: Scol.)

  摘要：

  Head-space volatiles obtained from male mountain pine beetles, Dendroctonus ponderosae, were analyzed by coupled CC-MS and chiral gas chromatography. 5-Ethyl-7-methyl-6,8-dioxabicyclo[3.2.1] (6) was found as a new naturally occurring isomer of brevicomin (1). In addition, several stereoisomers of 7-ethyl-5-methyl-6,8-dioxabicyclo[3.2.1] (11) and 1-(5-methyl-6,8-dioxabicyclo[3.2.1]octyl)ethanol (12) could be identified. Relative and absolute configurations of the compounds were determined by unambiguous syntheses, which are described. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0968-0896(96)00013-2