| 223391-98-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 223391-98-8；223137-25-5
• 化学式: C₃₂H₈F₂₀N₂O₄Pd₂
• 分子量: 1077.23
• InChiKey: NDAWYOLUQAMUCO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  [tetrabutylammonium]2[(Pd(pentafluorophenyl)2(μ-hydroxo))2] 、 氰乙酸甲酯 以 甲醇 为溶剂， 以91%的产率得到
  参考文献：
  名称：

  Reactivity of [{M(C₆F₅)₂(μ-OH)}₂]^2- (M = Pd or Pt) toward Aromatic Amines and Malononitrile

  摘要：

  Binuclear mu-hydroxo-mu-arylamido complexes [Pd-2(C6F5)(4)(mu-OH)(mu-NHR)](2-) (R = C6H5, C6H4-Cl-p, C6H4F-p) and di-mu-arylamido complexes [M-2(C6F5)(4)(mu-NHR)(2)](2-) (M = Pd, R = C6H5, C6H4Cl-p, C6H4F-p, C6H4NO2-p, C6F5; M == Pt, R = C6H4NO2-p, C6F5) have been prepared by reaction of [M-2(C6F5)(4)(mu-OH)(2)](2-) with the corresponding arylamine RNH2 in 1:1 or 1:2 molar ratio, respectively. The reaction of [Pd-2(C6F5)(4)(mu-NHPh)(2)](2-) with CS2 leads to the formation of the mononuclear dithiocarbamate complex [Pd(C6F5)(2)(S2CNHPh)](-). Malononitrile and methyl cyanoacetate react with [Pd-2(C6F5)(4)(mu-OH)(2)](2-) in methanol to give the binuclear complexes [Pd-2(C6F5)(4){mu-CH(CN)CN}(2)](2-) and [Pd-2(C6F5)(4){mu-CH(CO2Me)CN}(2)](2-). However the reaction of [Pd-2(C6F5)(4)(mu-OH)(2)](2-) with malononitrile in boiling methanol gives the mononuclear diiminato complex [Pd(C6F5)(2){NHC(OMe)CHC(OMe)NH}](-). In wet toluene [Pd-2-(C6F5)(4)(mu-OH)(2)](2-) produces the cyclotrimerization of malononitrile, giving 4,6-diamino-2-cyanomethyl-3,5-pyridinedicarbonitrile. The structures of [Pd-2(C6F5)(4)(mu-NHC6F5)(2)](2-) and [Pd-2(C6F5)(4){mu-CH(CN)CN}(2)](2-) have been determined by X-ray diffraction.

  DOI：

  10.1021/om980508z