(+)-Phenyl-2-octylphosphinsaeure | 64308-50-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (+)-Phenyl-2-octylphosphinsaeure
• 英文别名: (+)-Octyl-(2)-phenyl-phosphonsaeure；octan-2-yl(phenyl)phosphinic acid
• CAS: 64308-50-5
• 化学式: C₁₄H₂₃O₂P
• 分子量: 254.309
• InChiKey: QNZNGRLBRJBBSQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  (+)-Phenyl-2-octylphosphinsaeure-n-butylester 在 sodium hydroxide 、 lithium chloride 作用下， 生成 (+)-Phenyl-2-octylphosphinsaeure
  参考文献：
  名称：

  Electrophilic Substitution at Saturated Carbon. XXV. Structural Requirements for Functional Groups Centered around Second-Row Elements to Preserve Asymmetry of Carbanions^1,2

  摘要：

  DOI：

  10.1021/ja00964a025

文献信息

• SALTS OF PAROXETINE
  申请人：SMITHKLINE BEECHAM PLC

  公开号：EP1091958A1

  公开（公告）日：2001-04-18
• POLYCARBONATE WITH REDUCED COLOR
  申请人：Sabic Innovative Plastics IP B.V.

  公开号：EP2035500A2

  公开（公告）日：2009-03-18
• METHOD FOR MAKING MOLDED POLYCARBONATE ARTICLES WITH IMPROVED COLOR
  申请人：SABIC Innovative Plastics IP B.V.

  公开号：EP2041202B1

  公开（公告）日：2013-05-08
• POLYCARBONATES, COMPOSITIONS MADE THEREFROM, METHODS OF MANUFACTURE THEREOF, AND ARTICLES THEREFROM
  申请人：SABIC Innovative Plastics IP B.V.

  公开号：EP2370498A1

  公开（公告）日：2011-10-05
• Method for Making Molded Polycarbonate Articles with Improved Color
  申请人：Berndsen Sjef

  公开号：US20080004407A1

  公开（公告）日：2008-01-03

  A method for preparing a molded article includes the steps of (a) obtaining a polycarbonate resin and (b) molding the polycarbonate resin. The polycarbonate resin is made by a transesterification reaction using an activated diaryl carbonate such that the polycarbonate is susceptible to the formation of internal ester linkages (IEL). The method occurs with the proviso that the polycarbonate resin, the molding conditions or both are selected to control the amount of IEL formed during the molding process to a level of less than 0.4 mol %.