7-(2-bromoethyl)-2,5,6-trimethyl-1H-indene | 1126944-03-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: 7-(2-bromoethyl)-2,5,6-trimethyl-1H-indene
• CAS: 1126944-03-3
• 化学式: C₁₄H₁₇Br
• 分子量: 265.193
• InChiKey: PBSMNZZZRKLQOC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-(1-methoxy-2,5,6-trimethyl-2,3-dihydro-1H-inden-4-yl)ethanol 在 N-溴代丁二酰亚胺(NBS) 、 对甲苯磺酸 、 三苯基膦 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 1.25h， 生成 7-(2-bromoethyl)-2,5,6-trimethyl-1H-indene 、 4-(2-bromoethyl)-2,5,6-trimethyl-1H-indene
  参考文献：
  名称：

  Catalysts

  摘要：

  一种含有化合物（I）的配合物：在烯烃聚合催化剂的形成以及其在烯烃聚合中的应用中具有用处。

  公开号：

  US08569532B2

文献信息

• CATALYSTS
  申请人：VOSKOBOYNIKOV Alexander Zelmanovich

  公开号：US20120252993A1

  公开（公告）日：2012-10-04

  A complex containing a ligand of formula (I): useful in the formation of olefin polymerization catalysts and their use in olefin polymerization.

  含有化学式(I)的配体的复合物：在烯烃聚合催化剂的形成中有用，并且可用于烯烃聚合。
• US8569532B2
  申请人：——

  公开号：US8569532B2

  公开（公告）日：2013-10-29
• [EN] CATALYSTS<br/>[FR] CATALYSEURS
  申请人：BOREALIS TECH OY

  公开号：WO2009027075A2

  公开（公告）日：2009-03-05

  A complex comprising a ligand of formula (I), wherein each R1, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R1 groups on adjacent carbon atoms taken together may form an optionally substituted 5- to 8-membered fused ring; each R2, which may be the same or different is hydrogen, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy; an optionally substituted heteroaryl group, or an optionally substituted heterocyclyl group; R3, which binds to the 6-membered ring of the indenyl group, is -(Si(R5)2)p-, where p is 1 or 2, -(C(R5)2 )n- where n is an integer of 2 or more; each R4 which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, N(R5)2, silyl, siloxy, an optionally substituted heteroaryl group, an optionally substituted heterocyclyl group or two R4 groups on adjacent carbon atoms taken together can form an optionally substituted 5- to 8-membered fused carbon ring; each R5, which may be the same or different, is hydrogen, an optionally substituted C1-20 hydrocarbyl group, or two R5 groups taken together can form an optionally substituted 5- to 8-membered ring; a is 0 to 3; b is 0 to 3; c is 0 to 4; complexed to a metal ion, M.
• Catalysts
  申请人：Voskoboynik Alexander Zelmanovich

  公开号：US08569532B2

  公开（公告）日：2013-10-29

  A complex containing a ligand of formula (I): useful in the formation of olefin polymerization catalysts and their use in olefin polymerization.

  一种含有化合物（I）的配合物：在烯烃聚合催化剂的形成以及其在烯烃聚合中的应用中具有用处。