2-{3-[3-(benzo[b]naphtho[1,2-d]furan-8-yl)phenyl]phenyl}dibenzo[f,h]quinoxaline | 1609021-57-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并呋喃
• 英文名称: 2-{3-[3-(benzo[b]naphtho[1,2-d]furan-8-yl)phenyl]phenyl}dibenzo[f,h]quinoxaline
• 英文别名: 2-(benzo[b]naphtho[1,2-d]furan-8-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane；3-[3-(3-Naphtho[2,1-b][1]benzofuran-8-ylphenyl)phenyl]phenanthro[9,10-b]pyrazine；3-[3-(3-naphtho[2,1-b][1]benzofuran-8-ylphenyl)phenyl]phenanthro[9,10-b]pyrazine
• CAS: 1609021-57-9
• 化学式: C₄₄H₂₆N₂O
• 分子量: 598.703
• InChiKey: ZNZCYPBXKNMRMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.6
• 重原子数：
  47
• 可旋转键数：
  3
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3-氯-2-氟溴苯 在 N-甲基吡咯烷酮 、 四(三苯基膦)钯 、 正丁基锂 、 palladium diacetate 、 potassium carbonate 、 caesium carbonate 、 三(邻甲基苯基)磷 、 正丁基二(1-金刚烷基)膦 作用下， 以 四氢呋喃 、 1,4-二氧六环 、 乙醇 、 正己烷 、 水 、 甲苯 为溶剂， 反应 62.5h， 生成 2-{3-[3-(benzo[b]naphtho[1,2-d]furan-8-yl)phenyl]phenyl}dibenzo[f,h]quinoxaline
  参考文献：
  名称：

  [EN] HETEROCYCLIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  [FR] COMPOSÉ HÉTÉROCYCLIQUE, ÉLÉMENT ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTROLUMINESCENT, DISPOSITIF ÉLECTRONIQUE ET DISPOSITIF D'ÉCLAIRAGE

  摘要：

  提供一种新型的杂环化合物，可用作分散有发光物质的宿主材料。提供一种具有长寿命的发光元件。一种杂环化合物，其中通过具有6到13个碳原子的芳基基团连接了一个二苯并[f,h]喹喙基团和一个苯并[b]萘并[1,2-d]呋喃基团。二苯并[f,h]喹喙基团、苯并[b]萘并[1,2-d]呋喃基团和芳基基团分别未被取代，或具有1到4个碳原子的烷基基团或具有6到13个碳原子的芳基基团作为取代基。

  公开号：

  WO2014069613A1

文献信息

• Dibenzo[f,h]Quinoxaline Derivative, Method of Synthesizing the Same, Light-Emitting Element, Light-Emitting Device, Electronic Appliance, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20150080574A1

  公开（公告）日：2015-03-19

  A dibenzo[f,h]quinoxaline derivative in which impurities are reduced and a novel method of synthesizing the dibenzo[f,h]quinoxaline derivative in which impurities are reduced are provided. In addition, a light-emitting element, a light-emitting device, an electronic appliance, or a lighting device with high emission efficiency and high reliability in which the dibenzo[f,h]quinoxaline derivative is used as an EL material is provided. In the synthesis method, a 2-(chloroaryl)dibenzo[f,h]quinoxaline derivative is used as a synthetic intermediate in a synthetic pathway so that an impurity contained in a final product can be removed easily by purification by sublimation.

  提供一种二苯并[f,h]喹噁啉衍生物，其中杂质得到减少，并提供一种减少杂质的二苯并[f,h]喹噁啉衍生物的新合成方法。此外，提供一种使用二苯并[f,h]喹噁啉衍生物作为EL材料的发光元件、发光装置、电子设备或照明装置，具有高发射效率和高可靠性。在合成方法中，使用2-(氯芳基)二苯并[f,h]喹噁啉衍生物作为合成中间体，以便通过升华纯化轻松去除最终产品中含有的杂质。
• HETEROCYCLIC COMPOUND, LIGHT-EMITTING ELEMENT, LIGHT-EMITTING DEVICE, ELECTRONIC DEVICE, AND LIGHTING DEVICE
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20140124764A1

  公开（公告）日：2014-05-08

  To provide a novel heterocyclic compound capable of being used as a host material in which a light-emitting substance is dispersed. To provide a light-emitting element having a long lifetime. A heterocyclic compound in which a dibenzo[f,h]quinoxalinyl group and a benzo[b]naphtho[1,2-d]furanyl group are bonded through an arylene group having 6 to 13 carbon atoms. The dibenzo[f,h]quinoxalinyl group, the benzo[b]naphtho[1,2-d]furanyl group, and the arylene group separately are unsubstituted or have, as a substituent, an alkyl group having 1 to 4 carbon atoms or an aryl group having 6 to 13 carbon atoms.

  提供一种新型的杂环化合物，可用作分散发光物质的主体材料。提供一种寿命长的发光元件。该杂环化合物中，通过含有6到13个碳原子的芳基烃基，将一个二苯并[f，h]喹啉基团和一个苯并[b]萘[1,2-d]呋喃基团结合。二苯并[f，h]喹啉基团、苯并[b]萘[1,2-d]呋喃基团和芳基烃基分别未被取代或具有1到4个碳原子的烷基或6到13个碳原子的芳基作为取代基。
• Heterocyclic compound, light-emitting element, light-emitting device, electronic device, and lighting device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US10665791B2

  公开（公告）日：2020-05-26

  A novel heterocyclic compound that can be used as a host material in which a light-emitting substance is dispersed. A light-emitting element having a long lifetime. A heterocyclic compound in which a substituted or unsubstituted dibenzo[f,h]quinoxalinyl group is bonded to a substituted or unsubstituted arylene group having 6 to 25 carbon atoms which is bonded to any one of the 8-11 positions of a substituted or unsubstituted benzo[b]naphtho[1,2-d]furan skeleton.

  一种新型杂环化合物，可用作分散发光物质的主材料。寿命长的发光元件。一种杂环化合物，其中一个取代或未取代的二苯并[f,h]喹喔啉基团与一个具有 6 至 25 个碳原子的取代或未取代的芳烯基团键合，该芳烯基团与一个取代或未取代的苯并[b]萘并[1,2-d]呋喃骨架的 8-11 位中的任意一个位置键合。
• Heterocyclic Compound, Light-Emitting Element, Light-Emitting Device, Electronic Device, and Lighting Device
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20180083199A1

  公开（公告）日：2018-03-22

  A novel heterocyclic compound that can be used as a host material in which a light-emitting substance is dispersed. A light-emitting element having a long lifetime. A heterocyclic compound in which a substituted or unsubstituted dibenzo[f,h]quinoxalinyl group is bonded to a substituted or unsubstituted arylene group having 6 to 25 carbon atoms which is bonded to any one of the 8-11 positions of a substituted or unsubstituted benzo[b]naphtho[1,2-d]furan skeleton.
• US9368732B2
  申请人：——

  公开号：US9368732B2

  公开（公告）日：2016-06-14