[Ru(II)(4,4'-dimethyl-2,2'-bipyridine)2(1,2-bis(4'-methyl-2,2'-bipyridin-4-yl)ethane] | 1229702-05-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Ru(II)(4,4'-dimethyl-2,2'-bipyridine)2(1,2-bis(4'-methyl-2,2'-bipyridin-4-yl)ethane]
• CAS: 1229702-05-9
• 化学式: C₄₈H₄₆N₈Ru
• 分子量: 836.017
• InChiKey: KETKOZMPDOSKBO-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  ammonium hexafluorophosphate 、 五羰基氯铼(I) 、 [Ru(II)(4,4'-dimethyl-2,2'-bipyridine)2(1,2-bis(4'-methyl-2,2'-bipyridin-4-yl)ethane] 生成 [Ir(4,4′-dimethyl-2,2′-bipyridine)₂(1,2-bis(4′-methyl-[2,2′-bipyridin]-4-yl)ethane)Re(CO)_3Cl](PF₆)₂
  参考文献：
  名称：

  Conjugation effect of the bridging ligand on the CO2 reduction properties in difunctional photocatalysts

  摘要：

  The photocatalytic activity for CO2 reduction and optical and electrochemical properties of two RuII–ReI binuclear complexes [Ru(dmb)2LRe(CO)3Cl]2+ (Ru–Re and RuRe, dmb = 4,4′-dimethyl-2,2′-bipyridine) with 1,2-bis(4′-methyl-2,2′-bipyridyl-4-yl)ethane and 1,2-bis(4′-methyl-2,2′-bipyridyl-4-yl)ethene as bridging ligands have been investigated. The conjugation content of the bridging ligands plays an important role in the photocatalytic behavior: a saturated linkage exhibited more efficient than the conjugated.

  DOI：

  10.1039/c0dt00310g