1,1,2,2-Tetraphenyl-1,2-(dimethyl-3,3,3-trifluoropropylsiloxy)ethane | 345632-97-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: 1,1,2,2-Tetraphenyl-1,2-(dimethyl-3,3,3-trifluoropropylsiloxy)ethane
• 英文别名: [2-[Dimethyl(3,3,3-trifluoropropyl)silyl]oxy-1,1,2,2-tetraphenylethoxy]-dimethyl-(3,3,3-trifluoropropyl)silane
• CAS: 345632-97-5
• 化学式: C₃₆H₄₀F₆O₂Si₂
• 分子量: 674.874
• InChiKey: DSMLLFWMLLSIGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  11.22
• 重原子数：
  46
• 可旋转键数：
  13
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  二苯甲酮 、 氯二甲基-3,3,3-氟丙基硅烷 在 magnesium 、 1,1,3,3-四甲基脲 作用下， 以 四氢呋喃 为溶剂， 反应 14.0h， 以46%的产率得到1,1,2,2-Tetraphenyl-1,2-(dimethyl-3,3,3-trifluoropropylsiloxy)ethane
  参考文献：
  名称：

  Control of free-radical polymerization of 2,2,2-trifluoroethyl methacrylate (TEMA) by a substituted fluorinated tetraphenylethane-type INITER

  摘要：

  This paper deals with the free radical polymerization of 2,2.2-trifluoroethyl methacrylate (TEMA) initiated by a substituted fluorinated tetraphenylethane-type INITER.The synthesis of a new fluorinated substituted tetraphenylethane is described. This initiator, prepared from benzophenone: and 3,3,3(trifluoropropyl)chlorodimethylsilane behaves as an INITER when used to polymerize TEMA. In the first period of polymerization. telechelic oligomers are formed. They were isolated from the mixture and their structure was characterized by H-1-NMR spectroscopy, By thermal cleavage at the bonds between the last monomer unit and the end groups from the: initiates, these telechelic oligomers are effective initiators of further free-radical polymerization of ethylenic monomers, yielding block copolymers besides the respective homopolymer. Thus, in a second step, styrene was introduced into poly(TEMA) to produce block copolymers with a macroinitiator efficiency dose to 85%. (C) 2001 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0022-1139(00)00406-1

文献信息

• Control of free-radical polymerization of 2,2,2-trifluoroethyl methacrylate (TEMA) by a substituted fluorinated tetraphenylethane-type INITER
  作者：J. Roussel、B. Boutevin

  DOI：10.1016/s0022-1139(00)00406-1

  日期：2001.3

  This paper deals with the free radical polymerization of 2,2.2-trifluoroethyl methacrylate (TEMA) initiated by a substituted fluorinated tetraphenylethane-type INITER.The synthesis of a new fluorinated substituted tetraphenylethane is described. This initiator, prepared from benzophenone: and 3,3,3(trifluoropropyl)chlorodimethylsilane behaves as an INITER when used to polymerize TEMA. In the first period of polymerization. telechelic oligomers are formed. They were isolated from the mixture and their structure was characterized by H-1-NMR spectroscopy, By thermal cleavage at the bonds between the last monomer unit and the end groups from the: initiates, these telechelic oligomers are effective initiators of further free-radical polymerization of ethylenic monomers, yielding block copolymers besides the respective homopolymer. Thus, in a second step, styrene was introduced into poly(TEMA) to produce block copolymers with a macroinitiator efficiency dose to 85%. (C) 2001 Elsevier Science B.V. All rights reserved.