| 1234380-13-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1234380-13-2
• 化学式: C₅₈H₈₂HgN₄
• 分子量: 1035.91
• InChiKey: DKTQXKVNYHOFLM-UHFFFAOYSA-N

反应信息

• 作为反应物：
  描述：

  以 二氯甲烷-D2 为溶剂， 生成
  参考文献：
  名称：

  Taking Advantage of Hg−C Bonds: Synthesis of the First Homoleptic Bis-β-diketiminate Complex Bound through the γ-Carbons

  摘要：

  The most common beta-diketiminate ligand, [{N(2,6-(Pr2C6H3)-Pr-i)C(Me)}(2)CH](-) (BDI), was used to synthesize a new mercury complex in which two BDI ligands are bound to the metal through the gamma-carbons in the solid state. In solution, one of the BDI ligands switches to an N,N'-binding mode; this complex is in equilibrium with the homoleptic species. The thermodynamic parameters, Delta H degrees (-2.52 kcal mol(-1)), Delta S degrees (-9.24 cal mol(-1) K-1), and Delta G degrees(298) (0.23 kcal mol(-1)), were measured using variable-temperature H-1 NMR spectroscopy.

  DOI：

  10.1021/om100167e
• 作为产物：
  描述：

  (2-((2,6-diisopropylphenyl)amino)-4-((2,6-diisopropylphenyl)imino)-pent-2-ene) lithium salt 、 mercury dichloride 以 甲苯 为溶剂， 以34%的产率得到
  参考文献：
  名称：

  Taking Advantage of Hg−C Bonds: Synthesis of the First Homoleptic Bis-β-diketiminate Complex Bound through the γ-Carbons

  摘要：

  The most common beta-diketiminate ligand, [{N(2,6-(Pr2C6H3)-Pr-i)C(Me)}(2)CH](-) (BDI), was used to synthesize a new mercury complex in which two BDI ligands are bound to the metal through the gamma-carbons in the solid state. In solution, one of the BDI ligands switches to an N,N'-binding mode; this complex is in equilibrium with the homoleptic species. The thermodynamic parameters, Delta H degrees (-2.52 kcal mol(-1)), Delta S degrees (-9.24 cal mol(-1) K-1), and Delta G degrees(298) (0.23 kcal mol(-1)), were measured using variable-temperature H-1 NMR spectroscopy.

  DOI：

  10.1021/om100167e