Butyl-di-(3-hydroxypropyl)-phosphin | 6779-29-9

• 分子结构分类: 有机化合物 - 有机磷化合物 - 有机膦及其衍生物
• 英文名称: Butyl-di-(3-hydroxypropyl)-phosphin
• 英文别名: 3-[Butyl(3-hydroxypropyl)phosphanyl]propan-1-ol
• CAS: 6779-29-9
• 化学式: C₁₀H₂₃O₂P
• 分子量: 206.265
• InChiKey: KMUYQHBWFRJFTM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

文献信息

• Transition metal complexes and polymerization catalysts
  申请人：Otomaru Yuka

  公开号：US20060229195A1

  公开（公告）日：2006-10-12

  There are provided a transition metal complex of formula (1): wherein M represents an element of Group 6 of Periodic Table of Elements, A and A′ are the same or different, and represent a substituted or unsubstituted C1-10 alkylene group or the like, Y represents a substituted or unsubstituted C1-10 alkyl group, or the like, X 1 and X 2 are the same or different, and represent a hydrogen atom, a halogen atom, a substituted or unsubstituted C1-10 alkyl group, or an amino group disubstituted with C1-20 hydrocarbon, and n 1 is an integer of 0 to 3, an olefin polymerization catalyst obtained by combining a transition metal complex with an organic aluminum or aluminoxane, a polymerization catalyst further containing a boron compound, and a process for producing olefin polymer using the polymerization catalyst.

  提供了一种公式为（1）的过渡金属配合物：其中M代表元素周期表的第6组元素，A和A'相同或不同，代表取代或未取代的C1-10烷基或类似物，Y代表取代或未取代的C1-10烷基或类似物，X1和X2相同或不同，代表氢原子、卤素原子、取代或未取代的C1-10烷基或二取代C1-20碳氢化合物的氨基，n1为0至3的整数，通过将过渡金属配合物与有机铝或铝烷氧化物结合获得的烯烃聚合催化剂，进一步含有硼化合物的聚合催化剂，以及使用该聚合催化剂生产烯烃聚合物的方法。
• NOVEL MUCOLYTIC AGENTS
  申请人：JOHNSON Michael R.

  公开号：US20150307530A1

  公开（公告）日：2015-10-29

  Provided is a method of liquefying mucus from mucosal surfaces by administering compounds containing a phosphine group.

  提供了一种通过给予含有膦基团化合物的方法，使粘液从黏膜表面液化的方法。
• Flame retardant polyphenylene oxide composition
  申请人：FMC Corporation

  公开号：EP0040665A1

  公开（公告）日：1981-12-02

  Thermoplastic polyphenylene oxide compositions such as polyphenylene oxide that has been modified with high impact polystyrene are rendered fire retardant by the addition of an effective amount of a 3-hydroxyalkyl phosphine oxide such as n-butyl bis(3-hydroxypropyl) phosphine oxide.

  通过添加有效量的 3-羟基烷基氧化膦（如正丁基双（3-羟基丙基）氧化膦），可使热塑性聚苯醚组合物（如用高抗冲聚苯乙烯改性的聚苯醚）具有阻燃性。
• Method of oxidizing tertiary phosphines
  申请人：FMC Corporation

  公开号：EP0062024A1

  公开（公告）日：1982-10-06

  Tertiary-alkyl phosphines, such as tris-(3-hydroxypropyl) phosphine may be oxidized by heating in the presence of water and between about 0.1 and about 10% by weight of an acid catalyst at a temperature above about 100°C.

  叔烷基膦，如三-（3-羟基丙基）膦，可在水和约 0.1 至约 10%（重量）的酸催化剂存在下，在高于约 100°C 的温度下加热氧化。
• Flame retardant polyphenylene ether-styrene thermoplastic resin compositions
  申请人：FMC Corporation

  公开号：EP0074345A1

  公开（公告）日：1983-03-16

  A flame retardant polyphenylene ether-styrene resin composition having a UL-94 rating of V-1 or better, a heat distortion temperature greater than 87°C and a melt viscosity at 200°C of less than 2,000 poise is obtained by incorporating with said polyphenylene ether-styrene resin composition from 3 to 6 parts by weight of a triaryl phosphate and from about 2-1/2 to about 5 parts by weight of a 3-hydroxyalkyl phosphine oxide having the formula: wherein R, may be the same or a different radical selected from the group consisting of hydrogen and the methyl radicals, R2 is a redical of 4 to 8 carbon atoms and n is either zero or one.

  一种阻燃聚苯醚-苯乙烯树脂组合物，其 UL-94 等级为 V-1 或更高，热变形温度大于 87°C，200°C 时的熔融粘度小于 2,000 poise，其制备方法是在所述聚苯醚-苯乙烯树脂组合物中加入 3 至 6 份（按重量计）三芳基磷酸酯和约 2-1/2 至约 5 份（按重量计）3-羟基烷基氧化膦，其化学式如下： 其中 R，可以是从氢和甲基基组成的组中选出的相同或不同的基，R2 是 4 至 8 个碳原子的复数，n 是 0 或 1。