1,4,8,11,15,18,22,25-octa(6-hydroxyhexylthio)phthalocyaninato Zn(II) | 1399623-70-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 1,4,8,11,15,18,22,25-octa(6-hydroxyhexylthio)phthalocyaninato Zn(II)
• CAS: 1399623-70-1
• 化学式: C₈₀H₁₁₂N₈O₈S₈Zn
• 分子量: 1635.74
• InChiKey: UGHCHVSDYXYIJU-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  6-[[8,14,17,23,26,32,35-Heptakis(6-hydroxyhexylsulfanyl)-2,11,20,29,37,38,39,40-octazanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1(37),3(40),4,6,8,10,12,14,16,18,20,22,24,26,28(38),29,31,33,35-nonadecaen-5-yl]sulfanyl]hexan-1-ol 在 zinc diacetate 作用下， 以 戊醇 为溶剂， 反应 1.0h， 以310 mg的产率得到1,4,8,11,15,18,22,25-octa(6-hydroxyhexylthio)phthalocyaninato Zn(II)
  参考文献：
  名称：

  Towards near-infrared photosensitisation: a photosensitising hydrophilic non-peripherally octasulfanyl-substituted Zn phthalocyanine

  摘要：

  A Zn(II) phthalocyanine substituted with eight hydroxylated sulfanyl moieties in non-peripheral positions was designed to exhibit properties desired for photodynamic therapy: hydrophilicity, isomeric purity and near-infrared absorption in addition to high singlet oxygen generation. Photophysical and photochemical studies proved to be promising. (c) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.07.062