Dodecyl 2,6,9,13-tetraoxabicyclo[12.4.0]octadeca-1(18),14,16-trien-7-ylmethyl hydrogen phosphate | 144631-80-1

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 甘油磷脂
• 英文名称: Dodecyl 2,6,9,13-tetraoxabicyclo[12.4.0]octadeca-1(18),14,16-trien-7-ylmethyl hydrogen phosphate
• CAS: 144631-80-1
• 化学式: C₂₇H₄₇O₈P
• 分子量: 530.639
• InChiKey: RERGMYVEKSGCGE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  36
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.78
• 拓扑面积：
  92.7
• 氢给体数：
  1
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  dodecyl dichlorophosphate 、 9-(hydroxymethyl)-2,3-benzo-14-crown-4 生成 Dodecyl 2,6,9,13-tetraoxabicyclo[12.4.0]octadeca-1(18),14,16-trien-7-ylmethyl hydrogen phosphate
  参考文献：
  名称：

  Highly selective lithium ion transport and extraction with crowned alkyl phosphoric acid

  摘要：

  A series of benzo-14-crown-4 derivatives (3a-3c) having an ionizable alkyl phosphoric acid moiety as an additional binding site were synthesized. From the results of transport and extraction experiments, it is revealed that 3c exhibited a drastic enhancement in Li+ ion transport rate and extractability when compared with the corresponding hydroxymethyl derivative.

  DOI：

  10.1016/0040-4039(92)89039-f

文献信息

• Habata, Yoichi; Ikeda, Manami; Akabori, Sadatoshi, Journal of the Chemical Society. Perkin transactions I, 1992, # 20, p. 2651 - 2656
  作者：Habata, Yoichi、Ikeda, Manami、Akabori, Sadatoshi

  DOI：——

  日期：——