Dimethyl-monodeuteriomethyl-amin | 126476-14-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: Dimethyl-monodeuteriomethyl-amin
• 英文别名: Trimethylamin-d；deuteriomethyl-dimethyl-amine；1-deuterio-N,N-dimethylmethanamine
• CAS: 126476-14-0
• 化学式: C₃H₉N
• 分子量: 60.1032
• InChiKey: GETQZCLCWQTVFV-MICDWDOJSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Dimethyl-monodeuteriomethyl-amin 、 氯化苄 、 碘化钠 生成 N,N,N-trimethyl-1-phenylmethanaminium iodide
  参考文献：
  名称：

  COCKER, W.;GERAGHTY, N. W. A.;MCMURRY, T. B. H.;SHANNON, P. V. R., J. CHEM. SOC. PERKIN TRANS., 1984, N 10, 2245-2254

  摘要：

  DOI：
• 作为产物：
  描述：

  3,3-dideuteriopent-4-enyl(trimethyl)azanium;hydroxide 生成 Dimethyl-monodeuteriomethyl-amin
  参考文献：
  名称：

  COCKER, W.;GERAGHTY, N. W. A.;MCMURRY, T. B. H.;SHANNON, P. V. R., J. CHEM. SOC. PERKIN TRANS., 1984, N 10, 2245-2254

  摘要：

  DOI：

文献信息

• Platinum-Catalyzed Reduction of DMF by 1,1,3,3-Tetramethyldisiloxane, HMeSi₂OSiMe₂H: New Intermediates HSiMe₂OSiMe₂OCH₂NMe₂ and HSiMe₂(OSiMe₂)₃OCH₂NMe₂ and Their Further Chemical Reactivity
  作者：Jorge L. Martinez、Hemant K. Sharma、Renzo Arias-Ugarte、Keith H. Pannell

  DOI：10.1021/om500439p

  日期：2014.6.23

  The use of Karstedt's catalyst to study the reduction of Me2NCHO (DMF) by the popular "dual SiH"-containing tetramethyldisiloxane, HMe2SiOSiMe2H (1), has revealed that the first step in the process involves an initial single hydrosilylation to form HSiMe2OSiMe2OCH2NMe2 (3). This intermediate is readily isolated and purified via distillation. In the continued presence of the catalyst, 3 transforms to the transient tetrasiloxane HMe2SiOSiMe2OSiMe2OSiMe2OCH2NMe2 (4), along with the formation of Me3N. The tetrasiloxane 4 itself transforms to Me3N and (Me2SiO) (n = 4-6). Despite the demonstrated reactivity of 3, it can also be used to perform the expected metal-catalyzed hydrosilylation chemistry of the SiH group as well as reactions of the SiOCH2NMe2 functionality involving siloxane chain extension and is thus an important new reagent for siloxane chemistry.