| 1259967-63-9

• 分子结构分类: 有机化合物 - 有机硫化合物
• CAS: 1259967-63-9
• 化学式: C₂H₆O*C₁₀H₁₈CoN₈O₂S₂
• 分子量: 451.5
• InChiKey: SFVWXXCZSYKRTB-ZNKDCASJSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  乙醇 、 diacetyl monoxime thiosemicarbazone 、 cobalt(II) diacetate tetrahydrate 在 AgNO₃ 作用下， 以 乙醇 、 水 为溶剂， 生成
  参考文献：
  名称：

  Homometallic and Heterometallic Complexes of (E)-2-(E)-3-(hydroxyimino)butan-ylidene)hydrazinecarbothioamide

  摘要：

  The coordination characteristic of diacetylmonoxime thiosemicarbazone {IUPAC name (E)-2-(E)-3-(hydroxyimino)butan-2- ylidene)-hydrazinecarbothioamide} (H2L) towards Ag(I), Fe(III), Co(II), Ni(II), and Cu(II) individually and in combination with Ag(1) has been studied. The prepared complexes are characterized by microanalysis, thermal, magnetic and spectral (IR, 1H NMR, ESR, and electronic) studies. Ag(1) plays an important role in the complex formation. The ligand chelates as: i) neutral in [Ag(H2L)(H2O)]center dot NO3 center dot H2O, [Ag2(H2L)2]center dot 2NO3 center dot H2O and [Ag2(H2L)(OH)]center dot NO3; ii) monobasic in [Co(HL)2]center dot EtOH, [Fe(HL)2]center dot NO3, [FeAg2(HL)2(NO3)2]center dot NO3, and [Cu2(HL)2 (EtOH) (NO3)]center dot NO3 center dot EtOH and iii) dibasic molecule in [Ni(L) (EtOH)], [NiAg2(L)2(EtOH)], [NiAg2(L)(H2O)2]center dot 2NO3, [Cu2Ag2 (L)2(H2O)(NO3)]center dot NO3 and [Cu2Ag2(L)(H2O)3(OAc)2(NO3)]center dot NO3 center dot H2O. The variation in coordination may be due to the presence of two different metal ions and the preparation conditions. The inside and outside nitrates are investigated by IR spectra; the ionic by a strong band at approximate to 1380 cm-1 and the coordinated by bands at approximate to 1434 and approximate to 1211 cm-1. The outer sphere solvents are detected by IR and thermal analysis.

  DOI：

  10.1080/15533174.2010.509679