[(bipyrimidyldisulfide)Cu2I2]2 | 1023908-89-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [(bipyrimidyldisulfide)Cu2I2]2
• 英文别名: [(PymS)2Cu2I2]2
• CAS: 1023908-89-5
• 化学式: C₁₆H₁₂Cu₄I₄N₈S₄
• 分子量: 1206.39
• InChiKey: IFAIVLHOGWMBST-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  copper(l) iodide 、 2,2'-二硫代二-嘧啶 以 乙腈 为溶剂， 以50%的产率得到[(bipyrimidyldisulfide)Cu2I2]2
  参考文献：
  名称：

  Copper halide clusters and polymers supported by bipodal heteroelemental ligands

  摘要：

  The flexible, multi dentate, heteroelemental, dipodal ligands; bis(2pyridylthio)methane, (PyS)(2)CH2 (Py = pyridyl = C5H4N), (PymS)(2)CH2, bis(2pyrimidylthio)methane, and bipyrimidyidisulfide, (PymS)(2) (Pym = pyrimidine, C4H3N2), were reacted with a series of copper precursors to determine whether monomeric compounds, cubane clusters or polymeric chains would be obtained. Copper(II) chloride, copper(I) cyanide and copper(I) thiocyanate afforded infinite polymeric chains while copper(I) iodide afforded tetranuclear clusters supported by two ligand molecules. All products were characterized in the solid-state by X-ray crystallography. (C) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2008.01.005