2-Pyridin-2-yl-4-[2-(2-pyridin-2-ylpyridin-4-yl)ethyl]pyridine | 714218-17-4

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: 2-Pyridin-2-yl-4-[2-(2-pyridin-2-ylpyridin-4-yl)ethyl]pyridine
• CAS: 714218-17-4
• 化学式: C₂₂H₁₈N₄
• 分子量: 338.412
• InChiKey: SPKDRZFSZRFDKJ-UHFFFAOYSA-N

物化性质

• 沸点：
  523.3±45.0 °C(Predicted)
• 密度：
  1.181±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  顺-双(2,2'-二吡啶基)二氯化钌(II)二水合物 、 六氟磷酸钾 、 2-Pyridin-2-yl-4-[2-(2-pyridin-2-ylpyridin-4-yl)ethyl]pyridine 以 乙醇 为溶剂， 以57%的产率得到
  参考文献：
  名称：

  Synthesis of a new series of poly-2,2′-bipyridinyl ruthenium(II) complexes with polytopic ligands derived from 4-methyl-2,2′-bipyridine

  摘要：

  Five novel disymmetrical. ligands containing two or more 2,2'-bipyridine moieties covalently linked, belonging to 4, 5 or 8 coordination sites, have been synthesized with high yield, starting from previously prepared 4-methyl-2,2'-bipyridine. Their abilities to complex ruthenium(II) have been investigated as well as the determination of the main physico-chemical features of the resulting multinuclear complexes. (C) 2003 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2003.10.001

文献信息

• Highly efficient visible-light-driven CO₂ reduction to CO using a Ru(<scp>ii</scp>)–Re(<scp>i</scp>) supramolecular photocatalyst in an aqueous solution
  作者：Akinobu Nakada、Kazuhide Koike、Kazuhiko Maeda、Osamu Ishitani

  DOI：10.1039/c5gc01720c

  日期：——

  Even in an aqueous solution, a Ru(ii)–Re(i) supramolecular photocatalyst worked well for CO₂ reduction. A water-soluble reductant BI(CO₂⁻)H should be useful for evaluation of the real abilities of various photocatalytic systems.

  即使在水溶液中，Ru(ii)–Re(i)超分子光催化剂也能很好地用于CO₂还原。水溶性还原剂BI(CO₂⁻)H应该对评估各种光催化系统的真实能力有用。