2-<4-(2,3-Epoxy-propyloxy)-phenyl>-2-<4-allyloxy-phenyl>-propan | 140896-80-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-<4-(2,3-Epoxy-propyloxy)-phenyl>-2-<4-allyloxy-phenyl>-propan
• 英文别名: bisphenol A monoglycidyl ether；2-[[4-[2-(4-Prop-2-enoxyphenyl)propan-2-yl]phenoxy]methyl]oxirane
• CAS: 140896-80-6
• 化学式: C₂₁H₂₄O₃
• 分子量: 324.42
• InChiKey: UQSVHMCHXHYGEV-UHFFFAOYSA-N

物化性质

• 沸点：
  458.0±40.0 °C(Predicted)
• 密度：
  1.084±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5
• 重原子数：
  24
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  31
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  双酚A双烯丙基醚 在 双氧水 、 乙腈 、 potassium hydroxide 作用下， 以 甲醇 、 水 为溶剂， 反应 4.5h， 以25.7%的产率得到2-<4-(2,3-Epoxy-propyloxy)-phenyl>-2-<4-allyloxy-phenyl>-propan
  参考文献：
  名称：

  PROCESS FOR PRODUCTION OF EPOXY COMPOUND

  摘要：

  公开号：

  EP2518061B1

文献信息

• METHOD OF PRODUCING EPOXY COMPOUNDS
  申请人：Uchida Hiroshi

  公开号：US20110263882A1

  公开（公告）日：2011-10-27

  Provided is a method of efficiently producing an epoxy compound from an allyl ether having an aromatic ring under mild conditions by using hydrogen peroxide as an oxidizing agent without using an organic solvent. The method of producing an epoxy compound comprises reacting an allyl ether having an aromatic ring with hydrogen peroxide to epoxidize a carbon-carbon double bond of an allyl group to thereby produce a corresponding epoxy compound having an aromatic ring, wherein water only is used as a solvent without using an organic solvent, and a tungsten compound, and a tertiary amine and/or a quaternary ammonium salt, are used as a reaction catalyst.

  提供了一种在温和条件下使用过氧化氢作为氧化剂，而无需使用有机溶剂，从具有芳香环的烯丙基醚高效生产环氧化合物的方法。生产环氧化合物的方法包括将具有芳香环的烯丙基醚与过氧化氢反应，使烯丙基团的碳-碳双键环氧化，从而产生具有芳香环的相应环氧化合物，其中仅使用水作为溶剂，不使用有机溶剂，并且使用钨化合物、三级胺和/或季铵盐作为反应催化剂。
• PROCESS FOR PRODUCING EPOXY COMPOUND
  申请人：Nagato Nobuyuki

  公开号：US20120029217A1

  公开（公告）日：2012-02-02

  According to the present, invention, a process for producing an epoxy compound, where an epoxy compound can be selectively produced from olefins with good yield at low cost in a safe manner by a simple operation under mild conditions without using a quaternary ammonium salt or a metal compound, is provided. The present invention relates to a process for producing an epoxy compound, comprising epoxidizing a carbon-carbon double bond of an organic compound having a carbon-carbon double bond by using hydrogen peroxide as an oxidant, wherein the epoxidation is carried by out using an organic nitrile compound and an organic amine compound.

  根据本发明，提供了一种生产环氧化合物的方法，其中可以通过简单操作在温和条件下以低成本安全地从烯烃中选择性地生产环氧化合物，而无需使用季铵盐或金属化合物。本发明涉及一种生产环氧化合物的方法，包括使用过氧化氢作为氧化剂，通过使用有机腈化合物和有机胺化合物对含有碳碳双键的有机化合物的碳碳双键进行环氧化。
• Epoxy compound, mixture, composition, and cured product comprising same, method for preparing same, and use thereof
  申请人：KOREA INSTITUTE OF INDUSTRIAL TECHNOLOGY

  公开号：US10597412B2

  公开（公告）日：2020-03-24

  The present invention relates to a novel epoxy compound, a method for preparing same, a composition and cured product comprising same, and use thereof, wherein the compound shows excellent heat-resistant properties—specifically, a low thermal expansion property and a high glass transition temperature (including Tg-less which does not show a glass transition temperature), a flame retardant property and processability—specifically, a viscosity-control property, does not require a separate silane coupling agent, and has improved brittleness in a composite. According to one aspect of the present invention, provided are: an epoxy compound having at least one non-reactive silyl group, alkenyl group or combination thereof together with at least two epoxy groups and at least one alkoxysilyl group; a method for preparing the epoxy compound through alkoxysilylation and alkylsilylation; an epoxy composition comprising same; and a cured product.

  本发明涉及一种新型环氧化合物、制备方法、包含该化合物的组合物和固化产品及其用途，其中该化合物显示出优异的耐热性能--具体而言，低热膨胀性能和高玻璃化转变温度（包括不显示玻璃化转变温度的 Tg-less）、阻燃性能和加工性能--具体而言，粘度控制性能，不需要单独的硅烷偶联剂，并改善了复合材料的脆性。根据本发明的一个方面，提供了：具有至少一个非反应性硅烷基、烯基或其组合以及至少两个环氧基和至少一个烷氧基硅烷基的环氧化合物；通过烷氧基硅烷化和烷基硅烷化制备该环氧化合物的方法；包含该环氧化合物的环氧组合物；以及固化产品。
• ORGANOSILICONE COMPOSITIONS AND METHODS FOR PREPARING THEM
  申请人：Momentive Performance Materials Inc.

  公开号：EP2109635A1

  公开（公告）日：2009-10-21
• Organosilicone compositions and methods for preparing them
  申请人：Nesakumar Joseph Edward

  公开号：US20080255318A1

  公开（公告）日：2008-10-16

  Disclosed herein is a composition comprising a structure (M 1 ) a (M E ) b )D 1 ) c (D 2 ) d (T) e (Q) f , wherein M 1 =R 1 R 2 R 3 SiO 1/2 ; M E =R 4 R 5 R E SiO 1/2 ; D 1 =R 6 R 7 SiO 2/2 ; D 2 =R 8 R 9 SiO 2/2 ; T=R 10 SiO 3/2 ; and Q=SiO 4/2 ; wherein each R E is independently a monovalent hydrocarbon radical containing an epoxy group; R 9 comprises a structure -L 1 -Si(R 11 ) g (OR 12 ) 3-g or L 2 (D 3 ) h (M 2 ) i -L 3 -Si(R 13 ) g′ (OR 14 ) 3-g′ , wherein L 1 , L 2 , and L 3 are independently divalent linking groups; g and g′ independently have a value from 0 to 2; M 2 =R 15 R 16 R 17 SiO 1/2 ; D 3 =R 18 R 19 SiO 2/2 ; wherein R 1 , R 2 , R 3 , R 4 , R 5 , R 6 , R 7 , R 8 , R 10 , R 11 , R 12 , R 13 , R 14 , R 15 , R 16 , R 17 , R 18 , and R 19 are independently monovalent hydrocarbon radicals; wherein a, b, c, d, e, f, h, and i are stoichiometric subscripts that are zero or positive subject to the following limitations: b has a value of 2; d is greater than or equal to 1; when (a+c+e+f) is equal to zero, (b+d) is greater than or equal to 3; and when i=0, h is at least 1.