p-divinylphenethyldiethylchlorogermane | 671810-31-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: p-divinylphenethyldiethylchlorogermane
• 英文别名: poly(p-divinylphenethyldiethylchlorogermane)；Chloro[2-(4-ethenylphenyl)ethyl]diethylgermane；chloro-[2-(4-ethenylphenyl)ethyl]-diethylgermane
• CAS: 671810-31-4
• 化学式: C₁₄H₂₁ClGe
• 分子量: 297.364
• InChiKey: OXCRQSYSWRUAMS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  16
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.43
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  p-divinylphenethyldiethylchlorogermane 、 lithium aluminium tetrahydride 以 further solvent(s) 为溶剂， 生成 poly(p-divinylphenethyldiethylgermane)
  参考文献：
  名称：

  Preparation of polystyrene-supported hydrogermanes and their reduction of organic halides

  摘要：

  Polystyrene-supported hydrogermanes (1-4) were prepared by functionalization of polystyrenes or functionalization of a styrene followed by polymerization. The hydrogermanes, 1-4, reduced organic halides with or without a catalyst to give alkanes under mild conditions in the order: C-I>C-Br>C-Cl. The hydrogermanes, 1-4, were easily separated after use by filtering and could be regenerated with lithium aluminum hydride after their reactions with organic halides. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.09.034
• 作为产物：
  描述：

  对二乙烯苯 、 Diethylchlor-german 在 catalyst:azobis(isobutyronitrile) 作用下， 以 neat (no solvent) 为溶剂， 生成 p-divinylphenethyldiethylchlorogermane
  参考文献：
  名称：

  Preparation of polystyrene-supported hydrogermanes and their reduction of organic halides

  摘要：

  Polystyrene-supported hydrogermanes (1-4) were prepared by functionalization of polystyrenes or functionalization of a styrene followed by polymerization. The hydrogermanes, 1-4, reduced organic halides with or without a catalyst to give alkanes under mild conditions in the order: C-I>C-Br>C-Cl. The hydrogermanes, 1-4, were easily separated after use by filtering and could be regenerated with lithium aluminum hydride after their reactions with organic halides. (C) 2003 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2003.09.034

文献信息

• Preparation of polystyrene-supported hydrogermanes and their reduction of organic halides
  作者：Kunio Mochida、Kiyoko Amada、Hideo Sugimoto、Mitsuo Akiba、Katsuyuki Sato

  DOI：10.1016/j.poly.2003.09.034

  日期：2004.1

  Polystyrene-supported hydrogermanes (1-4) were prepared by functionalization of polystyrenes or functionalization of a styrene followed by polymerization. The hydrogermanes, 1-4, reduced organic halides with or without a catalyst to give alkanes under mild conditions in the order: C-I>C-Br>C-Cl. The hydrogermanes, 1-4, were easily separated after use by filtering and could be regenerated with lithium aluminum hydride after their reactions with organic halides. (C) 2003 Elsevier Ltd. All rights reserved.