4-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenol | 508231-88-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 4-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenol
• 英文别名: 4-Methoxy-2-(2-morpholin-4-ylethyliminomethyl)phenol
• CAS: 508231-88-7
• 化学式: C₁₄H₂₀N₂O₃
• 分子量: 264.324
• InChiKey: ZBBZYDAVDZYXLL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  19
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  54.3
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  copper(II) acetate monohydrate 、 4-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenol 、 sodium azide 以 甲醇 、 水 为溶剂， 反应 0.17h， 以51%的产率得到[CuL(μ_1,3-N₃)]_n·2nH₂O
  参考文献：
  名称：

  Azido and Thiocyanato-Bridged Polymeric Copper(II) Complexes [CuL(μ_1,3-N₃)]_n·2nH₂O and [CuL(μ_1,3-NCS)]_n: Synthesis and Structures

  摘要：

  A new azido-bridged polymeric copper(II) complex, [CuL((1,3)-N-3)](n)center dot 2nH(2)O (1), and a new thiocyanato-bridged polymeric copper(II) complex, [CuL((1,3)-NCS)](n) (2) (L = 4-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenolate), have been prepared and structurally characterized by elemental analysis, IR spectra, and single-crystal X-ray determination. Each Cu atom in the complexes is coordinated by three donor atoms of Schiff bases and by two atoms of the pseudohalide ligands, forming a square pyramidal geometry. Azide and thiocyanate anions are preferred bridging groups for the construction of polymeric copper complexes with Schiff bases.

  DOI：

  10.1080/15533174.2012.756019
• 作为产物：
  描述：

  N-(2-氨基乙基)吗啉 、 2-羟基-5-甲氧基苯甲醛 以 甲醇 为溶剂， 反应 0.5h， 生成 4-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenol
  参考文献：
  名称：

  Azido and Thiocyanato-Bridged Polymeric Copper(II) Complexes [CuL(μ_1,3-N₃)]_n·2nH₂O and [CuL(μ_1,3-NCS)]_n: Synthesis and Structures

  摘要：

  A new azido-bridged polymeric copper(II) complex, [CuL((1,3)-N-3)](n)center dot 2nH(2)O (1), and a new thiocyanato-bridged polymeric copper(II) complex, [CuL((1,3)-NCS)](n) (2) (L = 4-methoxy-2-[(2-morpholin-4-ylethylimino)methyl]phenolate), have been prepared and structurally characterized by elemental analysis, IR spectra, and single-crystal X-ray determination. Each Cu atom in the complexes is coordinated by three donor atoms of Schiff bases and by two atoms of the pseudohalide ligands, forming a square pyramidal geometry. Azide and thiocyanate anions are preferred bridging groups for the construction of polymeric copper complexes with Schiff bases.

  DOI：

  10.1080/15533174.2012.756019