1-(4-iodophenyl)cyclohexanecarbonitrile | 1260788-11-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-iodophenyl)cyclohexanecarbonitrile
• 英文别名: 1-(4-iodophenyl)cyclohexane-1-carbonitrile
• CAS: 1260788-11-1
• 化学式: C₁₃H₁₄IN
• 分子量: 311.165
• InChiKey: UILXQXBDZOQWOM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.2
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.46
• 拓扑面积：
  23.8
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(4-iodophenyl)cyclohexanecarbonitrile 在 二异丁基氢化铝 作用下， 生成 1-(4-iodophenyl)cyclohexanecarbaldehyde
  参考文献：
  名称：

  Fe催化的α-芳基醛的区域发散[1,2]-位移

  摘要：

  已经开发了通过 [1,2] 转移将醛催化转化为酮的方法。这种骨架重排显示出广泛的底物范围和化学选择性特征，同时表现出优异的 [1,2]-芳基或 [1,2]-烷基转移选择性，可通过电子效应轻松切换。

  DOI：

  10.1021/ja4068707
• 作为产物：
  描述：

  4-碘苯基乙腈, 、 alkaline earth salt of/the/ methylsulfuric acid 在 sodium hexamethyldisilazane 作用下， 生成 1-(4-iodophenyl)cyclohexanecarbonitrile
  参考文献：
  名称：

  Fe催化的α-芳基醛的区域发散[1,2]-位移

  摘要：

  已经开发了通过 [1,2] 转移将醛催化转化为酮的方法。这种骨架重排显示出广泛的底物范围和化学选择性特征，同时表现出优异的 [1,2]-芳基或 [1,2]-烷基转移选择性，可通过电子效应轻松切换。

  DOI：

  10.1021/ja4068707

文献信息

• TRANSISTORS AND METHODS FOR MAKING THEM
  申请人：Brown Beverley Anne

  公开号：US20140175409A1

  公开（公告）日：2014-06-26

  A semiconductor composition which comprises a soluble polyacene semiconductor and a polymeric semiconducting binder the binder having a permittivity greater than 3.4 at 000 Hz. The charge mobility of the semiconducting binder when measured in a pure state is greater than 10 −7 cm 2 /Vs and more preferably greater than 10 −6 cm 2 /Vs. Organic thin film transistors in which the source and drain electrodes are bridged by the semiconductor composition have desirable properties of reproducibility and charge mobility. The organic semiconducting composition can be applied by solution coating.

  一种半导体组合物，包括可溶性聚芴半导体和具有在000 Hz时介电常数大于3.4的聚合物半导体粘合剂。当纯态下测量半导体粘合剂的电荷迁移率大于10-7cm2/Vs，更好的是大于10-6cm2/Vs。源极和漏极电极由该半导体组合物桥接的有机薄膜晶体管具有可重复性和电荷迁移率的理想特性。该有机半导体组合物可通过溶液涂覆的方式应用。
• SEMICONDUCTOR COMPOUNDS
  申请人：Brown Beverley Anne

  公开号：US20140114040A1

  公开（公告）日：2014-04-24

  This invention comprises a semiconducting polymer having a permittivity greater than 3.4 at 1000 Hz and a charge mobility in the pure state greater than 10 −7 cm 2 V −1 s −1 and more preferably greater than 10 −6 cm 2 V −1 s −1 . Preferred polymers include repeating units of triarylamines which have specific cyano and/or alkoxy substitution. They are suitable for use in electronic components such as organic thin film transistors.

  该发明涉及一种具有介电常数大于1000 Hz时大于3.4，纯态下电荷迁移率大于10-7cm2V-1s-1，更好地大于10-6cm2V-1s-1的半导体聚合物。首选聚合物包括三芳胺的重复单元，其具有特定的氰基和/或烷氧基取代。它们适用于用于电子元件，例如有机薄膜晶体管。
• Semiconductor compounds
  申请人：Brown Beverley Anne

  公开号：US09406886B2

  公开（公告）日：2016-08-02

  This invention comprises a semiconducting polymer having a permittivity greater than 3.4 at 1000 Hz and a charge mobility in the pure state greater than 10−7 cm2V−1s−1 and more preferably greater than 10−6 cm2V−1s−1. Preferred polymers include repeating units of triarylamines which have specific cyano and/or alkoxy substitution. They are suitable for use in electronic components such as organic thin film transistors.

  该发明涉及一种半导体聚合物，其介电常数在1000赫兹时大于3.4，纯态下的电荷迁移率大于10-7cm2V-1s-1，更好地大于10-6cm2V-1s-1。首选的聚合物包括三芳基胺的重复单元，其具有特定的氰基和/或烷氧基取代。它们适用于电子元件，例如有机薄膜晶体管。
• Transistors and methods for making them
  申请人：Brown Beverley Anne

  公开号：US09431145B2

  公开（公告）日：2016-08-30

  A semiconductor composition which comprises a soluble polyacene semiconductor and a polymeric semiconducting binder the binder having a permittivity greater than 3.4 at 000 Hz. The charge mobility of the semiconducting binder when measured in a pure state is greater than 10−7 cm2/Vs and more preferably greater than 10−6 cm2/Vs. Organic thin film transistors in which the source and drain electrodes are bridged by the semiconductor composition have desirable properties of reproducibility and charge mobility. The organic semiconducting composition can be applied by solution coating.

  一种半导体组合物，包括可溶性聚芴半导体和具有介电常数大于3.4的聚合物半导体粘合剂。当在纯态下测量时，半导体粘合剂的电荷迁移率大于10-7 cm2/Vs，更好的是大于10-6 cm2/Vs。源和漏电极由该半导体组合物桥接的有机薄膜晶体管具有可重复性和电荷迁移率的理想特性。该有机半导体组合物可以通过溶液涂覆的方式应用。
• SEMICONDUCTOR COMPOSITIONS FOR ORGANIC TRANSISTORS
  申请人：NEUDRIVE LIMITED

  公开号：EP2715820B1

  公开（公告）日：2018-02-14