1-(3-Isopropylphenyl)-1-methylethylchlorid | 19936-08-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(3-Isopropylphenyl)-1-methylethylchlorid
• 英文别名: (3-Isopropylphenyl)-dimethylcarbinylchlorid；1-(α-chloro-isopropyl)-3-isopropyl-benzene；1-(α-Chlor-isopropyl)-3-isopropyl-benzol；1-(2-Chloropropan-2-yl)-3-propan-2-ylbenzene
• CAS: 19936-08-4
• 化学式: C₁₂H₁₇Cl
• 分子量: 196.72
• InChiKey: JLXSXLCMZQZKCS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3-异丙基-alpha,alpha-二甲基苄醇 在 盐酸 作用下， 生成 1-(3-Isopropylphenyl)-1-methylethylchlorid
  参考文献：
  名称：

  Rates of Solvolysis of the Alkylphenyldimethylcarbinyl Chlorides. Evidence for the Importance of Carbon-to-Carbon Hyperconjugative Contributions in Alkyl Groups^1,2

  摘要：

  DOI：

  10.1021/ja01565a035

文献信息

• Initiators for living carbocationic polymerization
  申请人：Kennedy Joseph

  公开号：US10472457B2

  公开（公告）日：2019-11-12

  In various embodiments, the present invention is directed to new low cost initiator compositions for use with the production of well-defined telechelic PIBs (by LC+P of isobutylene). In various other embodiments, the present invention is directed to methods for using these novel compositions as initiators for isobutylene (IB) and other cationically polymerizable monomers, such as styrene and its derivatives. In still other embodiments, the present invention is directed to structurally new, allyl (and chlorine) telechelic PIBs formed from these new initiator compositions and their derivatives (in particular, hydroxyl telechelic PIB and amine telechelic PIB). In yet other embodiments, the present invention is directed to structurally new polyurethanes, polyureas, and polyurethane ureas made using telechelic PIBs formed from these new initiator compositions.

  在各种实施方案中，本发明涉及用于生产定义明确的远切 PIB 的新型低成本引发剂组合物（通过异丁烯的 LC+P）。在其他各种实施方案中，本发明涉及将这些新型组合物用作异丁烯 (IB) 和其他阳离子可聚合单体（如苯乙烯及其衍生物）的引发剂的方法。在另一些实施方案中，本发明涉及由这些新型引发剂组合物及其衍生物（特别是羟基引发剂 PIB 和胺引发剂 PIB）形成的结构新颖的烯丙基（和氯）引发剂 PIB。在另一些实施例中，本发明涉及使用由这些新引发剂组合物形成的远志 PIB 制成的结构新的聚氨酯、聚氨酯和聚氨酯脲。
• NOVEL INITIATORS FOR LIVING CARBOCATIONIC POLYMERIZATION
  申请人：KENNEDY Joseph

  公开号：US20190127510A1

  公开（公告）日：2019-05-02

  In various embodiments, the present invention is directed to new low cost initiator compositions for use with the production of well-defined telechelic PIBs (by LC + P of isobutylene). In various other embodiments, the present invention is directed to methods for using these novel compositions as initiators for isobutylene (IB) and other cationically polymerizable monomers, such as styrene and its derivatives. In still other embodiments, the present invention is directed to structurally new, allyl (and chlorine) telechelic PIBs formed from these new initiator compositions and their derivatives (in particular, hydroxyl telechelic PIB and amine telechelic PIB). In yet other embodiments, the present invention is directed to structurally new polyurethanes, polyureas, and polyurethane ureas made using telechelic PIBs formed from these new initiator compositions.