dichlorozinc;pyridin-2-amine | 72665-18-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: dichlorozinc;pyridin-2-amine
• CAS: 72665-18-0
• 化学式: C₁₀H₁₂Cl₂N₄Zn
• 分子量: 324.528
• InChiKey: XEQIEWVIRSOKEQ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  2-氨基吡啶 、 zinc(II) chloride 在 activated charcoal 作用下， 以 乙醇 为溶剂， 以76.6%的产率得到dichlorozinc;pyridin-2-amine
  参考文献：
  名称：

  A tetrahedral coordination compound for second-order nonlinear optics: synthesis, crystal structure and SHG of Zn(2-NH2py)2Cl2

  摘要：

  A coordination compound with a tetrahedral molecular configuration, Zn(NH(2)py)(2)Cl-2(2-NH(2)py=2-aminopyridine), was prepared. It is transparent in the visible region and shows second harmonic generation (SHG) effect 8.0 times as strong as that of KDP. X-ray single crystal structure analysis reveals that all Zn(NH(2)py)(2)Cl-2 molecules are aligned in a fully parallel direction. The advantages and disadvantages of tetrahedral zinc coordination compounds as nonlinear optical (NLO) materials are discussed. The results may represent a novel strategy for designing a new class of transparent NLO materials. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00255-7