3-(Phenylselanyl)but-3-en-1-ol | 67649-87-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 3-(Phenylselanyl)but-3-en-1-ol
• 英文别名: 3-phenylselanylbut-3-en-1-ol
• CAS: 67649-87-0
• 化学式: C₁₀H₁₂OSe
• 分子量: 227.165
• InChiKey: HZVMFONZDDYSEU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.91
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  环氧乙烷 、 vinyl phenyl selenide 生成 3-(Phenylselanyl)but-3-en-1-ol
  参考文献：
  名称：

  Organoselenium chemistry. 4. Deprotonations with potassium diisopropylamide-lithium tert-butoxide. Alkylation of 1-(phenylseleno)alkenes and bis(phenylseleno) acetals

  摘要：

  DOI：

  10.1021/jo00413a044

文献信息

• Hydroselenation of alkynes using NaBH4/BMIMBF4: easy access to vinyl selenides
  作者：Eder J. Lenardão、Luiz G. Dutra、Maiara T. Saraiva、Raquel G. Jacob、Gelson Perin

  DOI：10.1016/j.tetlet.2007.09.042

  日期：2007.11

  A general and easy method for the synthesis of several vinyl selenides using NaBH4 and BMIMBF4 as a recyclable solvent is described. This efficient and improved method furnishes the corresponding vinyl chalcogenides preferentially with Z configuration. We also observed that when the same protocol was applied to phenyl acetylene, (E)-bis-phenylseleno styrene was obtained in good yield and with high selectivity. (c) 2007 Elsevier Ltd. All rights reserved.
• Regiospecific hydroselenation of terminal acetylenes using aluminum phenylselenolate anions
  作者：Miguel J. Dabdoub、Tânia M. Cassol、Antonio C.F. Batista

  DOI：10.1016/s0040-4039(96)02114-4

  日期：1996.12

  Regiospecific hydroselenation of terminal acetylenes using aluminum phenylselenolates afforded the 1-organyl-1-phenylseleno ethenes in good yields. The first example of exclusive formation of the hydroselenation Markovnikov adducts is described. Copyright (C) 1996 Elsevier Science Ltd
• Organoselenium chemistry. 4. Deprotonations with potassium diisopropylamide-lithium tert-butoxide. Alkylation of 1-(phenylseleno)alkenes and bis(phenylseleno) acetals
  作者：Stanley Raucher、Gary A. Koolpe

  DOI：10.1021/jo00413a044

  日期：1978.9