| 1268828-30-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• CAS: 1268828-30-3
• 化学式: C₁₃H₂₇N
• 分子量: 197.364
• InChiKey: UGAIYTWTXCVTNP-WYMLVPIESA-N

反应信息

• 作为产物：
  描述：

  正戊醛 、 辛胺 生成 、
  参考文献：
  名称：

  （E）-三氟甲基亚胺和Hy的无溶剂立体合成

  摘要：

  据报道，从相应的三氟甲基羰基化合物或其半缩醛开始合成三氟甲基酮亚胺，醛亚胺和的新的，绿色的和有效的策略。缩合反应在无溶剂条件下与一系列胺或肼进行，并以高立体选择性进行，始终仅以非常好的收率得到E-异构体。 氟化化合物-亚胺--立体选择性-缩合

  DOI：

  10.1055/s-0030-1258280

文献信息

• CATALYST COMPONENT FOR PROPYLENE POLYMERIZATION, PREPARATION METHOD THEREFOR AND CATALYST HAVING SAME
  申请人：China Petroleum&Chemical Corporation

  公开号：EP3135699A1

  公开（公告）日：2017-03-01

  The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compouns as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity. The obtained polymer has not only a wider molecular weight distribution, but also a high melt index and isotacticity.

  本发明公开了一种用于丙烯聚合的催化剂组分，由钛、镁、卤素和内部电子供体 A 组成，其中所述内部电子供体 A 选自如式 I 所示的化合物、 在式 I 中，R 选自氢、羟基和取代或未取代的 C1-C30 碳氢基，优选选自氢、羟基和取代或未取代的 C1-C20 烷基、C6-C30 芳基、C6-C30 杂芳基、C7-C30 烷芳基和 C7-C30 芳烷基；R1和R2可以彼此相同或不同，并且选自氢和取代或未取代的C1-C30烃基，优选选自氢和取代或未取代的C1-C20烷基、C6-C30芳基、C7-C30烷芳基和C7-C30芳烷基。根据本发明，使用如式 I 所示的化合物作为丙烯聚合的内部电子供体化合物，催化剂具有更高的活性，并且活性延迟的速度较慢。所得到的聚合物不仅分子量分布更广，而且熔融指数和等活度都很高。
• Catalyst component for propene polymerization, preparation method thereof, and catalyst containing the same
  申请人：China Petroleum & Chemical Corporation

  公开号：US10184017B2

  公开（公告）日：2019-01-22

  The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity. The obtained polymer has not only a wider molecular weight distribution, but also a high melt index and isotacticity.

  本发明公开了一种用于丙烯聚合的催化剂组分，由钛、镁、卤素和内部电子供体 A 组成，其中所述内部电子供体 A 选自如式 I 所示的化合物、 在式 I 中，R 选自氢、羟基和取代或未取代的 C1-C30 碳氢基，优选选自氢、羟基和取代或未取代的 C1-C20 烷基、C6-C30 芳基、C6-C30 杂芳基、C7-C30 烷芳基和 C7-C30 芳烷基；R1和R2可以彼此相同或不同，并且选自氢和取代或未取代的C1-C30烃基，优选选自氢和取代或未取代的C1-C20烷基、C6-C30芳基、C7-C30烷芳基和C7-C30芳烷基。根据本发明，使用如式 I 所示的化合物作为丙烯聚合的内部电子供体化合物，催化剂具有更高的活性，并且活性延迟的速度较慢。所得到的聚合物不仅分子量分布更广，而且熔融指数和等活度都很高。
• Catalyst Component for Propene Polymerization, Preparation Method Thereof, and Catalyst Containing the Same
  申请人：China Petroleum & Chemical Corporation

  公开号：US20170044280A1

  公开（公告）日：2017-02-16

  The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C 1 -C 30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C 1 -C 20 alkyl, C 6 -C 30 aryl, C 6 -C 30 heteroaryl, C 7 -C 30 alkylaryl and C 7 -C 30 arylalkyl; R 1 and R 2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C 1 -C 30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C 1 -C 20 alkyl, C 6 -C 30 aryl, C 7 -C 30 alkylaryl and C 7 -C 30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity. The obtained polymer has not only a wider molecular weight distribution, but also a high melt index and isotacticity.