[meso-5-(4-pyridinyl)octamethylporphyrinato]copper(II) | 194281-26-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: [meso-5-(4-pyridinyl)octamethylporphyrinato]copper(II)
• CAS: 194281-26-0
• 化学式: C₃₃H₃₁CuN₅
• 分子量: 561.189
• InChiKey: MPWIBNVNWXJIJM-ZUNRFPABSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  zinc tetraphenylporphyrin 、 [meso-5-(4-pyridinyl)octamethylporphyrinato]copper(II) 以 氯仿 为溶剂， 生成
  参考文献：
  名称：

  The coordination dimer from ZnTPP and M(m-PyOMP) (MH2 or Cu): spectroscopic properties and crystal structure

  摘要：

  The coordination dimer, which was formed by the linkage of meso-5-(pyridinyl)-octamethylporphyrin (H-2(m-PyOMP)) to (5,10,15,20-tetraphenylporphyrinato)zinc(II) (ZnTPP), was confirmed by proton NMR spectroscopy and fluorescence spectrophotometry. The coordinated diporphyrin demonstrated interporphyrin singlet state energy transfer with a rate contant of similar to 1.1x10(10) s(-1). The dimer that was composed of (5,10,15,20-tetraphenylporphyrinato)zinc and [meso-5-(pyridinyl)octamethylporphyrinato]crystallized in the monoclinic space group P2(1)/n with a=11.666(4), b=28.116(6), c=20.02(1) Angstrom, beta=106.97(5)degrees and Z=4. For 5275 observed reflections, the refinement yielded R=0.075. The presently-described non-covalent approach to donor-acceptor assembly provides a novel and useful approach to mimic the natural photosynthetic process.

  DOI：

  10.1016/s0020-1693(97)05476-5
• 作为产物：
  描述：

  meso-5-(4-pyridinyl)octamethylporphyrin 、 copper diacetate 以 甲醇 、 二氯甲烷 为溶剂， 生成 [meso-5-(4-pyridinyl)octamethylporphyrinato]copper(II)
  参考文献：
  名称：

  The coordination dimer from ZnTPP and M(m-PyOMP) (MH2 or Cu): spectroscopic properties and crystal structure

  摘要：

  The coordination dimer, which was formed by the linkage of meso-5-(pyridinyl)-octamethylporphyrin (H-2(m-PyOMP)) to (5,10,15,20-tetraphenylporphyrinato)zinc(II) (ZnTPP), was confirmed by proton NMR spectroscopy and fluorescence spectrophotometry. The coordinated diporphyrin demonstrated interporphyrin singlet state energy transfer with a rate contant of similar to 1.1x10(10) s(-1). The dimer that was composed of (5,10,15,20-tetraphenylporphyrinato)zinc and [meso-5-(pyridinyl)octamethylporphyrinato]crystallized in the monoclinic space group P2(1)/n with a=11.666(4), b=28.116(6), c=20.02(1) Angstrom, beta=106.97(5)degrees and Z=4. For 5275 observed reflections, the refinement yielded R=0.075. The presently-described non-covalent approach to donor-acceptor assembly provides a novel and useful approach to mimic the natural photosynthetic process.

  DOI：

  10.1016/s0020-1693(97)05476-5