RhCl2(η(5)-C5Me5)(PPh2(C6H4-3-C6F13)) | 252654-86-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: RhCl2(η(5)-C5Me5)(PPh2(C6H4-3-C6F13))
• 英文别名: dichlororhodium(1+);diphenyl-[3-(1,1,2,2,3,3,4,4,5,5,6,6,6-tridecafluorohexyl)phenyl]phosphane;1,2,3,4,5-pentamethylcyclopenta-1,3-diene
• CAS: 252654-86-7
• 化学式: C₃₄H₂₉Cl₂F₁₃PRh
• 分子量: 889.369
• InChiKey: SBDLMZUJJVZNQX-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  11.96
• 重原子数：
  51
• 可旋转键数：
  8
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.32
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  14

反应信息

• 作为产物：
  描述：

  dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer 、 PPh2(C6H4-3-C6F13) 以 乙醇 为溶剂， 以67%的产率得到RhCl2(η(5)-C5Me5)(PPh2(C6H4-3-C6F13))
  参考文献：
  名称：

  Synthesis and coordination chemistry of meta-perfluoroalkyl-derivatised triarylphosphines

  摘要：

  The synthesis and coordination chemistry of the PPhx(C6H4-3-C6F13)(3-x) (x=0, 1, 2) ligands containing perfluoroalkyl ponytails have been investigated. A comparison of the spectroscopic data for coordination complexes containing these ligands with those for complexes containing PPh3 or the related para-derivatised triarylphosphines indicates that these meta-derivatised ligands are slightly poorer sigma-donors and that steric crowding in the [PtCl2L2] complexes results in the formation of the normally thermodynamically less-favourable trans-isomers. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(99)00202-8