copper tetra-{4-[(3-methyl-1-phenyl-1H-pyrazol-5-yl)oxy]}phthalocyanine | 1442690-75-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: copper tetra-{4-[(3-methyl-1-phenyl-1H-pyrazol-5-yl)oxy]}phthalocyanine
• CAS: 1442690-75-6
• 化学式: C₇₂H₄₈CuN₁₆O₄
• 分子量: 1264.82
• InChiKey: RQKNFYSRHQXFJZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  4-[(3-methyl-1-phenyl-1H-pyrazol-5-yl)oxy]-phthalonitrile 、 copper diacetate 以32%的产率得到copper tetra-{4-[(3-methyl-1-phenyl-1H-pyrazol-5-yl)oxy]}phthalocyanine
  参考文献：
  名称：

  Synthesis and spectral properties of the metallophthalocyanines with the fragments of substituted pyrazoles

  摘要：

  By the reaction of 4-bromphthalonitrile with corresponding 1-phenyl-3-methyl-5-hydroxy- and 1-p-sulfophenyl-3-methyl-5-oxypyrazolaes the substituted phthalonitriles were synthesized and converted into metallophthalocyanines with the fragments of substituted pyrazoles. The compounds obtained were identified using the data of elemental analysis, gas chromatography-mass spectrometry, IR, H-1 NMR, and electronic spectroscopy. The influence of the peripheral environment of the phthalocyanine ligand in the resulting metal complexes on the spectral and other properties of the latter was revealed.

  DOI：

  10.1134/s1070363213040233