tris(2-triethylstannoxypropyl)amine | 181999-10-0

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: tris(2-triethylstannoxypropyl)amine
• 英文别名: 2-triethylstannyloxy-N,N-bis(2-triethylstannyloxypropyl)propan-1-amine
• CAS: 181999-10-0
• 化学式: C₂₇H₆₃NO₃Sn₃
• 分子量: 805.932
• InChiKey: UHQUOKRJUGKVFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  tris(2-triethylstannoxypropyl)amine 在 palladium diacetate 作用下， 以 乙醚 、 正戊烷 为溶剂， 反应 24.0h， 生成 1-cyclopropylmethyl-3,7,10-trimethylsilatrane
  参考文献：
  名称：

  Synthesis of 1-cyclopropylmethylsilatrane and 1-cyclopropylmethyl-3,7,10-trimethylsilatrane. Crystal structure of 1-cyclopropylmethylsilatrane

  摘要：

  1-Cyclopropylmethylsilatrane N(CH2CH2O)(3)SiCH2(sic) (2a) and 1-cyclopropylmethyl-3,7,10-trimethylsilatrane N(CH(2)CHMeO)(3)-SiCH2(sic) (2b) have been prepared in good yields by the reaction of the corresponding 1-allylsilatranes N(CH(2)CHRO)(3)SiCH2CH=CH2 (1) (R=H (a), Me (b)) with diazomethane in the presence of Pd(OAc)(2) as a catalyst, 1-Cyclopropylmethylsilatrane (2a) has also been synthesized from the reaction of cyclopropylmethyltriethoxysilane (3) with triethanolamine. Compounds 2a, 2b and 3 have been characterized by H-1 and C-13 NMR spectroscopy and elemental analyses, An X-ray structure determination of 2a indicates the presence of an N --> Si bond length of 2.149(4) Angstrom.

  DOI：

  10.1016/0022-328x(96)06430-3
• 作为产物：
  描述：

  triethylmethoxystannane 、 2,2’,2”-nitrilotris(propan-1-ol) 以 not given 为溶剂， 以98%的产率得到tris(2-triethylstannoxypropyl)amine
  参考文献：
  名称：

  通过有机金属（Si，Ge，Sn）试剂合成羧酸酯的Germatranyl衍生物

  摘要：

  三（2-羟烷基）胺的三烷基锡烷基酯，N（CH 2 CHROSnAlk 3）3（9-11（R = H，Me; Alk = Et，Bu），与X 3 GeC（R 1）（R 2）反应COOR 3（12 – 17）（X Cl或Br; R 1，R 2 = H，Me，Ph，SiMe 3，COOEt; R 3 = Me，Et）得到α-香叶烷基羧酸酯N（CH 2 CHRO）3 GeC（R 1）（R 2）-COOR 3（1 – 8），产量高。酯的合成12 - 17进行报告。通过用Et 3 SnOMe处理二苯乙烯酮得到原位Et 3 SnC（Ph 2）COOMe（23），然后与GeCl 4反应得到原位Cl 3 GeC（α），可以得到α-香叶烷基二苯基乙酸24和25的酯。pH值2）COOMe（22，并进一步反应9或11的germatrane，分别减少6上LiAlH 4乙醚中的H 2 O 3导致锗-碳键断裂，随后形成

  DOI：

  10.1002/cber.19971300611

文献信息

• New approach to 1-(phenylethynyl)germatranes and 1-(phenylethynyl)-3,7,10-trimethylgermatrane. Reactions of 1-(phenylethynyl)germatrane with N-bromosuccinimide and bromine
  作者：Sergey S Karlov、Pavel L Shutov、Andrei V Churakov、Jörg Lorberth*、Galina S Zaitseva*

  DOI：10.1016/s0022-328x(01)00708-2

  日期：2001.5

  Reaction of N(CH2CHRO)3GeBr (2a, b) with LiCCPh affords N(CH2CHRO)3GeCCPh (1a, b) (a, R=H; b, R=Me). Compound (1b) was also obtained by treatment of Cl3GeCCPh (3) with N(CH2CHMeOSnEt3)3 (4). (1a) reacts with N-bromosuccinimide to yield N(CH2CH2O)3GeC(Br)2C(O)Ph (5). Cis-N(CH2CH2O)3GeC(Br)C(Br)Ph (6) is formed by the reaction of 1a with Br2 in equivalent amounts. All compounds were characterized

  的N（CH反应2 CHRO）3 GEBR（图2a，2b）与LiCCPh得到N（CH 2 CHRO）3 GeCCPh（1A，b）（一，R = H; b，R = Me）的。化合物（1B）也被处理的Cl得到3 GeCCPh（3）与N（CH 2 CHMeOSnEt 3）3（4）。（1a）与N-溴琥珀酰亚胺反应生成N（CH 2 CH 2 O）3 GeC（Br）2 C（O）Ph（5）。通过1a与等价量的Br 2的反应形成顺式-N（CH 2 CH 2 O）3 GeC（Br）C（Br）Ph（6）。所有化合物均通过1 H-和13 C-NMR光谱和质谱进行表征。通过X射线衍射研究确定了1a和6的单晶结构。
• Synthesis and Characterisation of 1-[9-(H, Me3Si, Me3Ge, Me3Sn)9-Fluorenyl]-3,7,10-trimethylgermatranes. The Crystal Structure Analysis of 1-(9-Fluorenyl)-3,7,10-trimethylgermatrane
  作者：Galina S. Zaitseva、Sergei S. Karlov、Gleb V. Pen'kovoy、Andrei V. Churakov、Judith A. K. Howard、Bettina A. Siggelkow、Evgueni V. Avtomonov、Jörg Lorberth

  DOI：10.1002/(sici)1521-3749(199904)625:4<655::aid-zaac655>3.0.co;2-n

  日期：1999.4

  The title compounds, viz. C13H8(R)Ge . (OCHMeCH2)(3)N (1: R = H, 2: R = Me3Si; 3: R = Me3Ge) were prepared as mixtures of diastereomers by the reaction of N(CH(2)CHMeOSnAlk(3))(3) (7: Alk = Et; 8: Alk = Bu) with C13H8(R)GeBr3 (4: R=H, 5: R=Me3Si; 6: R=Me3Ge), respectively. The synthesis of C13H8(Me3Sn)Ge (OCHMeCH2)(3)N (13) by the reaction of germatrane (1) with Me3SnNMe2 is reported. Identity and structures were established by elemental analyses,H-1 and C-13 NMR spectroscopy and mass spectrometry. The crystal structure of 1 was determined by X-ray diffraction methods.