| 1220187-54-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• CAS: 1220187-54-1
• 化学式: C₂₂H₂₄N₂O₂Pd
• 分子量: 454.865
• InChiKey: DEACWIKXVJWGEY-MRVMGEECSA-L

反应信息

• 作为产物：
  描述：

  palladium diacetate 、 以 甲醇 、 乙腈 为溶剂， 生成
  参考文献：
  名称：

  Salen-type nickel(II), palladium(II) and copper(II) complexes having chiral and racemic camphoric diamine components

  摘要：

  Chiral and racemic Salen-type Schiff-base ligands (H(2)L(1), H(2)L(2) and H(2)L(3)), condensed between D-(+)- and D,L-camphoric diamine (also known as (1R,3S)-1,2,2-trimethylcyclopentane-1,3-diamine) and 2-hydroxybenzaldehyde or 3,5-dibromo-2-hydroxybenzaldehyde with a 1,2 molar ratio, have been synthesized and characterized. A series of new nickel(II), palladium and copper(II) complexes of these chiral and racemic ligands exhibiting different coordination number (4, 5 and 6) have been characterized with the formulae [NiL(1)]CH(3)OH (3), [NiL(1)]H(2)O (4), [NiL(2)] (5), [PdL(2)] (6), [Cu(2)(L(2))(2)(H(2)O)] (7) and [NiL(3)(DMF)(H(2)O)] (8) Different solvent molecules in 3 and 4 (methanol and water molecules) as well as different apical ligands in 7 and 8 (water and DMF molecules) are involved in different O-H O hydrogen bonding interactions to further stabilize the structures. UV-Vis (W-Vis), circular dichroism (CD) spectra and thermogravimetric (TG) analyses for the metal complexes have also been carried Out. (C) 2009 Elsevier Ltd. All rights reserved

  DOI：

  10.1016/j.poly.2009.12.021