Ni(2,6-bis((diisopropylphosphino)methyl)phenyl)(N=C(H)Ph) | 809279-47-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Ni(2,6-bis((diisopropylphosphino)methyl)phenyl)(N=C(H)Ph)
• 英文别名: benzylideneazanide;[3-[di(propan-2-yl)phosphanylmethyl]benzene-2-id-1-yl]methyl-di(propan-2-yl)phosphane;nickel(2+)
• CAS: 809279-47-8
• 化学式: C₂₇H₄₁NNiP₂
• 分子量: 500.267
• InChiKey: OWVRGFBDBZFMQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  Ni(2,6-bis((diisopropylphosphino)methyl)phenyl)(NH2) 以 苯 为溶剂， 生成 Ni(2,6-bis((diisopropylphosphino)methyl)phenyl)(N=C(H)Ph)
  参考文献：
  名称：

  Synthesis and Reactivity of a Mononuclear Parent Amido Nickel Complex. Structures of Ni[C₆H₃-2,6-(CH₂PⁱPr₂)₂](NH₂) and Ni[C₆H₃-2,6-(CH₂PⁱPr₂)₂](OMe)

  摘要：

  The first example of a nickel parent amido complex, Ni(PCP)(NH2), has been synthesized and structurally characterized. This compound reacts quantitatively with water and methanol to give the mononuclear hydroxide and methoxide derivatives Ni(PCP)(OH) and Ni(PCP)(OMe). Ni(PCP)(NH2) behaves as a strong nucleophile and adds rapidly to benzaldehyde, affording an equimolecular mixture of the aldimido derivative Ni(PCP)(N=CHPh), the hydroxide Ni(PCP)(OH), and ammonia.

  DOI：

  10.1021/om049312r