4-[[4-(甲基氨基)环己基]甲基]环己烷-1-胺 | 648900-91-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 4-[[4-(甲基氨基)环己基]甲基]环己烷-1-胺
• 英文名称: N-methyl-4,4'-diaminodicyclohexylmethane
• 英文别名: 4-[(4-Aminocyclohexyl)methyl]-N-methylcyclohexan-1-amine；4-[[4-(methylamino)cyclohexyl]methyl]cyclohexan-1-amine
• CAS: 648900-91-8
• 化学式: C₁₄H₂₈N₂
• 分子量: 224.39
• InChiKey: MUQUKEWKOIUWBO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  2-[(4-氨基苯)甲基]苯胺 、 N-甲基-4,4′-甲撑二苯胺 、 4,4'-二氨基二苯甲烷 在 ruthenium on aluminium oxide 氢气 作用下， 以 四氢呋喃 为溶剂， 生成 (2R,4R,5R,6S)-2,5-二(羟甲基)-6-(哌啶-3-氧基)二氢-2H-吡喃-2,3,3,4,5(4H)-五唑(non-preferredname) 、 4-[[4-(甲基氨基)环己基]甲基]环己烷-1-胺 、 4,4'-二氨基二环己基甲烷
  参考文献：
  名称：

  [EN] PROCESS FOR INCREASING THE SELECTIVITY OF THE HYDROGENATION OF 4,4'-DIAMINODIPHENYLMETHANE TO 4,4'-DIAMINODICYCLOHEXYLMETHANE IN THE PRESENCE OF AN N-ALKYL-4,4'-DIAMINODIPHENYLMETHANE
  [FR] PROCEDE D'AUGMENTATION DE LA SELECTIVITE DE L'HYDROGENATION DE 4,4'-DIAMINODIPHENYLMETHANE EN 4,4'-DIAMINODICYCLOHEXYLMETHANE EN PRESENCE D'UN N-ALKYL-4,4'-DIAMINODIPHENYLMETHANE

  摘要：

  公开号：

  WO2004007425A3

文献信息

• Sidewall functionalization of carbon nanotubes with organosilanes for polymer composites
  申请人：WILLIAM MARSH RICE UNIVERSITY

  公开号：EP2067741A1

  公开（公告）日：2009-06-10

  The present invention is directed to methods of functionalizing carbon nanotubes (CNTs), particularly single-wall carbon nanotubes (SWNTs), with organosilane species, wherein such functionalization enables fabrication of advanced polymer composites. The present invention is also directed toward the functionalized CNTs, advanced CNT-polymer composites made with such functionalized CNTs, and methods of making such advanced CNT-polymer composites.

  本发明涉及用有机硅烷使碳纳米管（CNTs），特别是单壁碳纳米管（SWNTs）功能化的方法，其中这种功能化可以制造高级聚合物复合材料。本发明还涉及功能化碳纳米管、用这种功能化碳纳米管制造的高级碳纳米管-聚合物复合材料，以及制造这种高级碳纳米管-聚合物复合材料的方法。
• Ophthalmic devices comprising photochromic materials with reactive substituents
  申请人：Johnson & Johnson Vision Care, Inc.

  公开号：US11256002B2

  公开（公告）日：2022-02-22

  Various non-limiting embodiments of the present disclosure relate to ophthalmic devices comprising photochromic materials comprising a reactive substituent. For example, the present disclosure contemplates ophthalmic devices comprising photochromic materials, such as photochromic naphthopyrans and indeno-fused naphthopyrans having a reactive substituent comprising a reactive moiety linked to the photochromic naphthopyran by one or more linking groups. In certain non-limiting embodiments, the reactive moiety comprises a polymerizable moiety. In other non-limiting embodiments, the reactive moiety comprises a nucleophilic moiety. Other non-limiting embodiments of the present disclosure relate to methods of making the photochromic ophthalmic device, wherein the photochromic ophthalmic devices comprise the photochromic naphthopyrans described herein.

  本公开的各种非限制性实施方案涉及到由包含反应性取代基的光致变色材料组成的眼科设备。例如，本公开考虑了包含光致变色材料的眼科设备，如光致变色萘并吡喃和茚并融合萘并吡喃，这些材料具有活性取代基，活性取代基包括通过一个或多个连接基团与光致变色萘并吡喃连接的活性分子。在某些非限制性实施方案中，活性分子包括可聚合分子。在其它非限制性实施方案中，反应基包括亲核基。本公开的其它非限制性实施方案涉及光致变色眼科装置的制造方法，其中光致变色眼科装置包括本文所述的光致变色萘烷。
• NOVEL SILICON-CONTAINING ALICYCLIC POLYIMIDE RESIN, POLYAMIC ACID RESIN, AND MANUFACTURING METHOD FOR SAME
  申请人：Kikuchi Tooru

  公开号：US20130158225A1

  公开（公告）日：2013-06-20

  A polyimide resin including repeating units represented by formula (1): wherein R is a diamine residue or a diisocyanate residue; m is an integer of 2 to 30; any of silicon atoms bonded to norbornane rings is in exo configuration with respect to the norbornane rings; and any of imide rings bonded to the norbornane rings is in exo configuration with respect to the norbornane rings, and a polyamic acid resin including repeating units represented by formula (2): wherein R is a diamine residue; m is an integer of 2 to 30; any of silicon atoms bonded to norbornane rings is in exo configuration with respect to the norbornane rings; and any of amide groups and carboxyl groups bonded to the norbornane rings is in exo configuration with respect to the norbornane rings. The polyimide resin is soluble in general-purpose solvents, has a good transparency and a high molecular weight, and is excellent in mechanical properties, such as tensile strength and elongation.
• Methods of Making Fused Ring Compounds
  申请人：Transitions Optical, Inc.

  公开号：US20170050909A1

  公开（公告）日：2017-02-23

  The present invention relates to methods of making fused ring compounds, such as indeno-fused naphthols, and fused ring indenopyran compounds, such as indeno-fused naphthopyrans, that each employ an unsaturated compound represented by the following Formula II. Referring to the unsaturated compound of Formula II: Ring-A can be selected from optionally substituted aryl (e.g., phenyl); m can be, for example, from 0 to 4; R 1 for each m can be selected from optionally substituted hydrocarbyl (e.g., C 1 -C 6 alkyl) optionally interrupted with at least one linking group (e.g., —O—); and R 3 and R 16 can each be independently selected from, for example, hydrogen or optionally substituted hydrocarbyl, such as C 1 -C 8 alkyl. When Ring-A is a phenyl group, the unsaturated compound represented by Formula II can be referred to as an unsaturated indanone acid/ester compound, or an indenone acid/ester compound (depending on whether R 16 is hydrogen, or an optionally substituted hydrocarbyl group).
• Photochromic Thienochromene Compounds
  申请人：Transitions Optical, Inc.

  公开号：US20180051037A1

  公开（公告）日：2018-02-22

  The present invention relates to photochromic compounds, such as thienochromene compounds represented by the following Formulas (1a) and/or (1b). The present invention also relates to photochromic compositions and articles containing one or more such photochromic thienochromene compounds.