(N,N'-phenylenebis(3,5-di-tert-butylsalicylideneimine))Zn(2,5-lutidine) | 1028157-82-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (N,N'-phenylenebis(3,5-di-tert-butylsalicylideneimine))Zn(2,5-lutidine)
• CAS: 1028157-82-5
• 化学式: C₄₃H₅₅N₃O₂Zn
• 分子量: 711.319
• InChiKey: RKKREDSCFWOMOI-XIDIDSRISA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  2,5-二甲基吡啶 、 (N,N'-phenylenebis(3,5-di-tert-butylsalicylideneimine))zinc 以 乙腈 为溶剂， 生成 (N,N'-phenylenebis(3,5-di-tert-butylsalicylideneimine))Zn(2,5-lutidine)
  参考文献：
  名称：

  Supramolecular Adsorption of Alkaloids by Metallosalphen Complexes

  摘要：

  Mono and bis-zinc(II)-centered salphen derivatives 1-5 are presented as efficient adsorption materials for pyridine-based alkaloid derivatives. The different alkaloid assemblies were studied by UV-vis and NMR spectroscopy, and high binding constants (K, similar to 10(5)) were additionally determined for the supramolecular complexes based on nicotine. X-ray analyses furthermore revealed, together with spectroscopic. solution data, a preferential positioning of the nicotine guest(s). Upon binding to bis-Zn-II-bis-salphen complexes, the dinicotine assembly provokes a colorimetric change that may be useful for colorimetric analyses. The adsorption/desorption process of nicotine was studied using a polymeric bis-Zn(salphen) complex (5) and showed a recycling potential of this type of complexes in the binding of alkaloid compounds.

  DOI：

  10.1021/ic702257e