1,3-di(o-salicylaldiminophenylthio)propane | 152367-73-2

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: 1,3-di(o-salicylaldiminophenylthio)propane
• 英文别名: 1,3-bis-(o-salicylaldiminophenylthio)propane；2-[[2-[3-[2-[(2-Hydroxyphenyl)methylideneamino]phenyl]sulfanylpropylsulfanyl]phenyl]iminomethyl]phenol
• CAS: 152367-73-2
• 化学式: C₂₉H₂₆N₂O₂S₂
• 分子量: 498.67
• InChiKey: FVAPLNDNSHOYOC-UHFFFAOYSA-N

物化性质

• 沸点：
  726.5±60.0 °C(predicted)
• 密度：
  1.19±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.9
• 重原子数：
  35
• 可旋转键数：
  10
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  116
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  1,3-di(o-salicylaldiminophenylthio)propane 、 copper diacetate 以 乙醇 为溶剂， 生成
  参考文献：
  名称：

  某些大环多齿铜（II），镍（II）和钴（II）配合物的合成，光谱和氧化还原行为

  摘要：

  中性四齿二胺的铜（II）配合物，以及由上述二胺和水杨醛或2-羟基-苯胺衍生的新型二元六齿席夫碱的一系列铜（II），镍（II）和钴（II）配合物已经制备了1-萘醛，并通过元素分析，磁化率以及红外光谱和电子光谱研究对其进行了表征。还研究了铜（II）和钴（II）配合物的电化学行为以及所有铜（II）配合物的ESR光谱参数。配体场强随螯合物环尺寸从六增加到七而增加。ESR光谱数据表明，铜（II）配合物呈现单体扭曲的八面体或拟四面体结构。乙腈中的II / Cu I和Co II / Co I对。

  DOI：

  10.1016/0277-5387(95)00182-r

文献信息

• Complexes of hexadentate NSO donor ligands—II. Copper(II) complexes of 1,3-di(o-salicylaldiminophenylthio)propane and 1,2-di(o-salicylaldiminophenylthio)xylene
  作者：Shefali Pal、Sailendra Nath Poddar、Saktiprosad Ghosh、Gurucharan Mukherjee

  DOI：10.1016/0277-5387(95)00110-e

  日期：1995.9

  tridentate chelating agents, leaving one-half of the ligands free. In all these complexes the copper(II) acceptor centre is present in a square-planar environment, the fourth coordination site being occupied either by a chloride ion or a water molecule. The EPR parameters (lowest g < 2.03) indicate their rhombic symmetry. All the complexes are found to exhibit quasi-reversible CuIII/CuII couples in their cyclic

  所述六齿二元席夫碱配体1,3-二（ø -SAlicylaldiminophenylthio）丙烷（H 2 DSALPTP）和1,2-二（ø -SAlicylaldiminophenylthio）二甲苯（H 2 DSALPTX），用N 2小号2 ö 2供体原子，与铜（II）盐，CuX 2 '· n H 2 O（X'= Cl，NO 3，ClO 4和n（分别为2、3和6），得到的络合物中配体的柔韧性质在其作为一元三齿螯合剂的作用中得以体现，而使一半的配体游离。在所有这些络合物中，铜（II）受体中心都存在于正方形平面环境中，第四个配位位点被氯离子或水分子占据。EPR参数（最低g <2.03）指示其菱形对称性。发现所有络合物在室温下于二氯甲烷溶液中的循环伏安图中均表现出准可逆的Cu III / Cu II对。
• Iron(III) complexes of hexadentate NSO-donor ligands, 1,3-di(o-salicylaldiminophenylthio)propane and 1,2-di(o-salicylaldiminophenylthio)xylene
  作者：Shefali Pal、Sailendra Nath Poddar、Gurucharan Mukherjee

  DOI：10.1016/s0277-5387(00)83071-5

  日期：1993.10

  Iron(III) complexes of hexadentate Schiff base N2S2O2 donor ligands, 1,3-di-(o-salicylaldiminophenylthio)propane (H2DSALPTP) and 1,2-di(o-salicylaldiminophenylthio)xylene (H2DSALPTX) have been synthesized and characterized. The ligands gave dark green iron(III) complexes [Fe(DSALPTP)]FeCl4 and [Fe(DSALPTX)]FeCl4 when reacted with anhydrous FeCl3. The Mossbauer data of these two complexes suggest the presence of two iron sites, one of which is octahedral and the other tetrahedral. The octahedral site is the complex cationic species and the tetrahedral site is the anion FeCl4-. On the other hand, Fe(ClO4)3.6H2O reacted with the ligands to give the complexes [Fe(DSALPTP)]ClO4 and [Fe(DSALPTX)]ClO4. The iron(III) centre in the complex cationic species of the first two complexes are low-spin and for the latter two complexes high-spin. Though a colour change from yellow to green occurred when the ligands reacted with Fe(NO3)3-9H2O, no compound could be isolated in the solid state from the solution.
• Complexes of hexadentate nso donor ligands-III. Nickel(II) complexes of 1,3-di(o-salicylaldiminophenylthio)propane and 1,2-di(o-salicylaldiminophenylthio)xylene
  作者：Shefali Pal、Saktiprosad Ghosh、Gurucharan Mukherjee、Asok Kumar Nandi

  DOI：10.1016/s0277-5387(98)00127-2

  日期：1998.9

  Nickel(II) complexes of the hexadentate N2S2O2 donor ligands, 1,3-di(o-salicylaldiminophenylthio)propane (H(2)DSALPTP) and 1,2-di(o-salicylaldiminophenylthio)xylene (H(2)DSALPTX) have been synthesised and characterised. H(2)DSALPTP reacted with NiCl2.6H(2)O or Ni(ClO4)(2).6H(2)O in presence of ammonia to give the complex [Ni(DSALPTP)] (1). H(2)DSALPTX reacted smoothly with N(ClO4)(2) to yield the corresponding complex [Ni(DSALPTX)] (2). The ligand did not react with NiCl2 in the absence of ammonia but in its presence produced the complex (2). The molecular and crystal structure;of [Ni(DSAL PTX)] exhibits a very unusual deployment of the six donor sites of the ligand. It crystallises in the orthorhombic system with space group P2(1)2(1)2(1). In dichloromethane solution both the complexes are found to exhibit Ni(II)/Ni(III) redox couples in their cyclic voltammograms at room temperature with E-1/2 values 0.87 and 0.78 V (vs. Ag/AgCl). (C) 1998 Elsevier Science Ltd. All rights reserved.