12,12-di(propan-2-yl)-12-silatricyclo[13.4.0.04,9]nonadeca-1(19),4,6,8,15,17-hexaen-2,10,13-triyne;nickel | 188483-39-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 12,12-di(propan-2-yl)-12-silatricyclo[13.4.0.04,9]nonadeca-1(19),4,6,8,15,17-hexaen-2,10,13-triyne;nickel
• CAS: 188483-39-8
• 化学式: C₂₄H₂₂NiSi
• 分子量: 397.214
• InChiKey: GRKSTWDNXIEGFR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  bis(1,5-cyclooctadiene)nickel (0) 、 12,12-di(propan-2-yl)-12-silatricyclo[13.4.0.04,9]nonadeca-1(19),4,6,8,15,17-hexaen-2,10,13-triyne 以 苯 为溶剂， 以85%的产率得到12,12-di(propan-2-yl)-12-silatricyclo[13.4.0.04,9]nonadeca-1(19),4,6,8,15,17-hexaen-2,10,13-triyne;nickel
  参考文献：
  名称：

  Planar Silicon and Germanium Heterocyclotriynes and Their Isomorphous Nickel(0) Complexes

  摘要：

  The syntheses of three strained silicon or germanium heterocyclotriynes, from the dilithium dianion of 2,2'-diethynyltolane (Li-2(OBET)) and the dialkyldichlorosilanes or dialkyldichlorogermane, are described. Reactions of the heterocyclynes with Ni(COD)2 give the nickel(0) complexes in very high yield. The heterocyclynes and their nickel complexes have been characterized by a variety of spectral techniques, and the X-ray crystal structures of compounds Si(i-Pr)(2)(oBET), Ni[Si(i-Pr)(2)(OBET)], SiPh2(OBET), Ni[SiPh2(OBET)], GePh2-(OBET), and Ni[GePh2(OBET)] are reported. The heterocyclynes and their nickel complexes possess isomorphous structures.

  DOI：

  10.1021/om960868r