6H-dibenzo<1,2>thiazine | 230-23-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻嗪类
• 英文名称: 6H-dibenzo<1,2>thiazine
• 英文别名: 6H-benzo[c][1,2]benzothiazine
• CAS: 230-23-9
• 化学式: C₁₂H₉NS
• 分子量: 199.276
• InChiKey: BUBOMQMCSMTMPS-UHFFFAOYSA-N

物化性质

• 沸点：
  394.1±25.0 °C(Predicted)
• 密度：
  1.233±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  37.3
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6H-dibenzo<1,2>thiazine 在 silver perchlorate 、 sodium hydride 作用下， 以 二氯甲烷 为溶剂， 反应 169.0h， 生成 6-benzyl-5-methyl-6H-dibenzo<1,2>thiazin-5-ium perchlorate
  参考文献：
  名称：

  Shimizu, Hiroshi; Ikedo, Koji; Hamada, Koji, Journal of the Chemical Society. Perkin transactions I, 1991, # 7, p. 1733 - 1747

  摘要：

  DOI：
• 作为产物：
  描述：

  2--2'-nitrobiphenyl 在 氢氧化钾 、 N-氯代丁二酰亚胺 、 lithium aluminium tetrahydride 、 正丁基锂 作用下， 以 苯 为溶剂， 反应 14.5h， 生成 6H-dibenzo<1,2>thiazine
  参考文献：
  名称：

  Shimizu, Hiroshi; Ikedo, Koji; Hamada, Koji, Journal of the Chemical Society. Perkin transactions I, 1991, # 7, p. 1733 - 1747

  摘要：

  DOI：

文献信息

• Syntheses and properties of novel cyclic sulfilimines, 2-azathiabenzene derivatives.
  作者：HIROSHI SHIMIZU、KAZUNORI MATSUO、TADASHI KATAOKA、MIKIO HORI

  DOI：10.1248/cpb.32.4360

  日期：——

  Novel cyclic sulfilimines (so-called azathiabenzenes), 2-methyl-1-aza-2-thianaphthalene (7) and 9-methyl-(14a) or 9-ethyl-10-aza-9-thiaphenanthrene (14b), were synthesized in high yields by deprotonation of the corresponding azasulfonium salts (6, 13a, 13b) with base. The ylidic properties of the azathiabenzenes were revealed by spectral and chemical evidence. The azathiabenzenes (14a, 14b) were easily oxidized with potassium permanganate to yield the corresponding azathiabenzene oxides (18a, 18b). Thermolysis of 14a in refluxing xylene afforded the ring-expanded product 7H-dibenzo [d, e] [1, 3] thiazepine (21), while 14b underwent β-elimination on refluxing in xylene to give 6H-dibenzo [c, e] [1, 2] thiazine (24). Reactions of the azathiabenzene derivatives with dimethyl acetylenedicarboxylate as an electrophile are also reported.

  通过用碱对相应的偶氮锍盐（6、13a、13b）进行去质子化，高产率地合成了新型环状亚磺酰亚胺（即偶氮苯）、2-甲基-1-氮杂-2-噻吩萘（7）和 9-甲基-（14a）或 9-乙基-10-氮杂-9-噻吩蒽（14b）。光谱和化学证据揭示了氮杂二苯乙烯的酰基性质。硫氮苯（14a、14b）很容易被高锰酸钾氧化，生成相应的硫氮苯氧化物（18a、18b）。14a 在回流二甲苯中发生热分解，得到环状扩展产物 7H-二苯并[d, e] [1, 3] 硫氮杂卓（21），而 14b 在二甲苯中回流发生 β-消除反应，得到 6H-二苯并[c, e] [1, 2] 硫氮杂卓（24）。此外，还报道了以乙炔二甲酸二甲酯为亲电体的氮杂环丁烷苯衍生物的反应。
• LIGHT-EMITTING DEVICE AND ELECTRONIC APPARATUS INCLUDING SAME
  申请人：Samsung Display Co., Ltd.

  公开号：US20220024958A1

  公开（公告）日：2022-01-27

  A light-emitting device includes a first compound represented by Formula 1; and a second compound, a third compound, a fourth compound, or any combination thereof, each having a specific formula: emitting device may have excellent driving voltage, current density, high luminescence efficiency, and long lifespan, and may be used in the manufacture of a high quality electronic apparatus.

  一种发光装置包括第一化合物，其由公式1表示；以及第二化合物、第三化合物、第四化合物或其任意组合，每种化合物都具有特定的化学式。该发光装置可能具有出色的驱动电压、电流密度、高发光效率和长寿命，并可用于制造高品质的电子设备。
• LIGHT-EMITTING DEVICE, ELECTRONIC APPARATUS INCLUDING THE SAME, AND ORGANOMETALLIC COMPOUND
  申请人：Samsung Display Co., Ltd.

  公开号：US20220013738A1

  公开（公告）日：2022-01-13

  Provided are an organometallic compound represented by Formula 1, a light-emitting device including the same, and an electronic apparatus including the light-emitting device. The light-emitting device includes: a first electrode; a second electrode facing the first electrode; and interlayer between the first electrode and the second electrode and including an emission layer, wherein the emission layer includes an organometallic compound represented by Formula 1.

  提供的是一个由公式1表示的有机金属化合物，包括该化合物的发光装置，以及包括该发光装置的电子设备。该发光装置包括：第一电极；面向第一电极的第二电极；以及位于第一电极和第二电极之间并包括发射层的中间层，其中发射层包括由公式1表示的有机金属化合物。
• ACRYLAMIDE DERIVATIVE, POLYMER COMPOUND AND PHOTORESIST COMPOSITION
  申请人：Aratani Ichihiro

  公开号：US20130230802A1

  公开（公告）日：2013-09-05

  To provide an acrylamide derivative which can form a structural unit of a polymer to be incorporated into a photoresist composition, a polymer produced through polymerization of a raw material containing the acrylamide derivative, and a photoresist composition which contains the polymer and which, as compared with the case of conventional ones, realizes formation of a high-resolution resist pattern having improved LWR. The invention provides an acrylamide derivative represented by the following formula (1): wherein R 1 represents a hydrogen atom, a methyl group, or a trifluoromethyl group; W represents a C1 to C10 alkylene group or a C3 to C10 cycloalkylene group; R 2 represents a cyclic group having 3 to 20 ring-forming atoms and represented by the following formula (2): wherein X represents an oxygen atom or >N—R 3 ; R 3 represents a hydrogen atom or a C1 to C5 alkyl group; Y represents >C═O or >S(═O) n ; and n is an integer of 0 to 2.

  为提供一种可以形成聚合物结构单元的丙烯酰胺衍生物，该聚合物可纳入到光刻胶组合物中，通过含有该丙烯酰胺衍生物的原料的聚合制备的聚合物以及包含该聚合物的光刻胶组合物，与传统情况相比，实现了形成具有改善LWR的高分辨率光刻胶图案。该发明提供了由以下公式（1）表示的丙烯酰胺衍生物：其中R1代表氢原子、甲基或三氟甲基；W代表C1到C10的烷基或C3到C10的环烷基；R2代表具有3到20个环形成原子的环状基团，由以下公式（2）表示：其中X代表氧原子或>N—R3；R3代表氢原子或C1到C5的烷基；Y代表>C═O或>S(═O)n；n为0到2的整数。
• Benzindolocarbazole Derivative, Light-Emitting Element Material Produced Using Same, and Light-Emitting Element
  申请人：TORAY INDUSTRIES, INC.

  公开号：US20150280140A1

  公开（公告）日：2015-10-01

  The present invention provides an organic thin film light emitting device having high luminous efficiency and durable life realized by using a benzindolocarbazole derivative as represented by either general formula (1-1) or (1-2) given below: [Chemical compound 1] wherein R 1 to R 24 may be identical to or different from each other and are selected from the group consisting of a hydrogen atom, alkyl group, cycloalkyl group, heterocyclic group, amino group, alkenyl group, cycloalkenyl group, alkynyl group, alkoxy group, alkylthio group, aryl ether group, aryl thioether group, aryl group, heteroaryl group, halogen atom, carbonyl group, carboxyl group, oxycarbonyl group, carbamoyl group, silyl group, and —P(═O)R 25 R 26 ; R 25 and R 26 represent either an aryl group or a heteroaryl group; R 25 and R 26 may be condensed to form a ring; L 1 to L 4 independently represent a single bond, a substituted or unsubstituted arylene group, or a substituted or unsubstituted heteroarylene group; and A 1 to A 4 independently represent an amino group, aryl group, heterocyclic group, or heteroaryl group.

  本发明提供了一种有机薄膜发光装置，其具有高发光效率和耐久寿命，该装置是通过使用如下通式（1-1）或（1-2）所示的苯并咯吡唑衍生物实现的：[化合物1]其中R1至R24可以相同也可以不同，且选择自氢原子、烷基、环烷基、杂环基、氨基、烯基、环烯基、炔基、烷氧基、烷硫基、芳基醚基、芳基硫醚基、芳基、杂芳基、卤素原子、羰基、羧基、氧羰基、氨基甲酰基、硅烷基和—P(═O)R25R26的群组中；R25和R26表示芳基或杂芳基；R25和R26可以缩合形成环；L1至L4独立地表示单键、取代或未取代芳基烷基或取代或未取代杂芳基烷基；以及A1至A4独立地表示氨基、芳基、杂环基或杂芳基。