4-[羟基(苯基)磷酰基]苯甲酸 | 106384-34-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-[羟基(苯基)磷酰基]苯甲酸
• 英文名称: (4-carboxyphenyl)phenylphosphinic acid
• 英文别名: -phenylphosphinsaeure；<4-Carboxy-phenyl>-phenyl-phosphinsaeure；4-[Hydroxy(phenyl)phosphoryl]benzoic acid
• CAS: 106384-34-3
• 化学式: C₁₃H₁₁O₄P
• 分子量: 262.202
• InChiKey: BFSMULOSYIQCGJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  18
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  Chlor-phenyl-p-tolyl-phosphin 在 sodium hydroxide 、 potassium permanganate 作用下， 反应 10.0h， 以37.6 g的产率得到4-[羟基(苯基)磷酰基]苯甲酸
  参考文献：
  名称：

  Solubilities of 2-Carboxyethylphenylphosphinic Acid and 4-Carboxyphenylphenylphosphinic Acid in Water

  摘要：

  The solubilities of 2-carboxyethylphenylphosphinic acid (CEPPA) and a potential reactive flame retardant, 4-carboxyphenylphenylphosphinic acid (CPPPA), in water were measured. The concentration of the solution was determined by sodium hydroxide titration with phenolphthalein as the indicator. The solubilities of CEPPA were measured from 25.10 degreesC to 76.32 degreesC with an uncertainty of 2.2%, and the solubilities of CPPPA were measured from 26.70 degreesC to 94.52 degreesC with an uncertainty of 2.1%.

  DOI：

  10.1021/je0340396

文献信息

• Thermoplastic Resin Composition For Masterbatches, Method Of Producing Molding Material Thereof, And Thermoplastic Resin Composition Using Them And Method Of Production Thereof
  申请人：Sato Maki

  公开号：US20070194479A1

  公开（公告）日：2007-08-23

  The present invention related to a thermoplastic resin composition for masterbatches, comprising an organophosphorus compound represented by General Formula (1): wherein R 1 and R 2 each represent an organic group or a halogen atom, and m and n each represent an integer of 0 to 4, and when m or n is an integer of 2 to 4, R 1 and R 2 may be the same or different, and a thermoplastic resin, wherein the thermoplastic resin composition for masterbatches contains a phosphorus content of 5000 ppm or more. The thermoplastic resin composition for masterbatches can easily be molded even when it has high phosphorus content and thus flame retardancy.
• Solubilities of 2-Carboxyethylphenylphosphinic Acid and 4-Carboxyphenylphenylphosphinic Acid in Water
  作者：Zhong-Wei Wang、Qi-Xin Sun、Jun-Sheng Wu、Li-Sheng Wang

  DOI：10.1021/je0340396

  日期：2003.7.1

  The solubilities of 2-carboxyethylphenylphosphinic acid (CEPPA) and a potential reactive flame retardant, 4-carboxyphenylphenylphosphinic acid (CPPPA), in water were measured. The concentration of the solution was determined by sodium hydroxide titration with phenolphthalein as the indicator. The solubilities of CEPPA were measured from 25.10 degreesC to 76.32 degreesC with an uncertainty of 2.2%, and the solubilities of CPPPA were measured from 26.70 degreesC to 94.52 degreesC with an uncertainty of 2.1%.