N-2-hydroxybenzyl-2-hydroxy-1-naphthaldimino-piperidinonickel(II) | 187607-01-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N-2-hydroxybenzyl-2-hydroxy-1-naphthaldimino-piperidinonickel(II)
• CAS: 187607-01-8
• 化学式: C₂₃H₂₄N₂NiO₂
• 分子量: 419.146
• InChiKey: UJFRRFKFIXRDOZ-SWFGUFHISA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  哌啶 、 2-hydroxy-1-naphthaldehyde-o-hydroxybenzyl amine 、 nickel(II) acetate tetrahydrate 以 甲醇 、 乙腈 为溶剂， 以31%的产率得到N-2-hydroxybenzyl-2-hydroxy-1-naphthaldimino-piperidinonickel(II)
  参考文献：
  名称：

  Some complexes of Nickel(II) with Ono Type Schiff Bases and their Monoligand Adducts. Part II.

  摘要：

  Coordination compounds of Ni(II) with four ONO-type Schiff bases, namely, N-2-hydroxybenzylsalicylaldimine (I), N-2-hydroxy-1-naphthylmethylsalicylaldimine (II), N-2-hydroxybenzyl-2-hydroxy-1-naphthaldimine (III) and N-2-hydroxy-1-naphthylmethyl-2-hydroxy-1-naphthaldimine (IV) have been studied. The ligands (III) and (IV) were found to form complexes of the composition NiL(2) (where L represents the Schiff base). The Ni(II) complexes of Schiff bases (I) and (II) were not obtained in crystalline form. In the presence of n-butylamine, however, all Schiff bases formed Ni(II) complexes of the composition NiL'(2), where L' represents Schiff bases formed by an amine exchange between L and n-butylamine. Furthermore, in the presence of piperidine, (I), (II), (III) and (IV) gave complexes of the composition NiLL '', (L '' is piperidine). Since all the complexes are diamagnetic, the coordination of Ni(II) was considered to be square-planar.

  DOI：

  10.1080/00945719708000179