Ag(2-chloronicotinate) | 1378236-19-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Ag(2-chloronicotinate)
• CAS: 1378236-19-1
• 化学式: Ag*C₆H₃ClNO₂
• 分子量: 264.417
• InChiKey: LCPXVWUDQXNDRS-UHFFFAOYSA-M

反应信息

• 作为产物：
  描述：

  2-氯烟酸 、 silver perchlorate 以 甲醇 为溶剂， 以45%的产率得到Ag(2-chloronicotinate)
  参考文献：
  名称：

  Synthesis, Structure, and Photoluminescent Property of a Novel 2D Silver(I) Polymer Based on Short Ag-Ag Interactions

  摘要：

  A new two-dimensional (2D) polymer, [Ag(2-Clnic)](n) (2-Clnic=2-chloronicotinate) (1), has been synthesized and characterized by IR, elemental analysis, single-crystal X-ray diffraction, and luminescence spectroscopy. X-ray crystal analysis reveals that complex 1 is constructed through pi-pi stacking and Ag center dot center dot center dot O interactions, which provide important roles in the assembly of intriguing structures and specific photophysical properties. In the solid state at room temperature, 1 is found to be luminescent with a purple emission band at 411 nm upon excitation at 360 nm.

  DOI：

  10.1080/15533174.2011.613437