[Fe(5,10,15-tris(pentafluorophenyl)corrolate)(NO)] | 340165-40-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Fe(5,10,15-tris(pentafluorophenyl)corrolate)(NO)]
• 英文别名: Fe(III)(NO)(TF5PC)
• CAS: 340165-40-4
• 化学式: C₃₇H₈F₁₅FeN₅O
• 分子量: 879.326
• InChiKey: RBJYTZAKRIORQN-XDBICYDFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  Fe^IV(5,10,15-tris(pentafluorophenyl)corrole)Cl 在 sodium nitrite 作用下， 以 二氯甲烷 、 水 为溶剂， 反应 3.0h， 生成 [Fe(5,10,15-tris(pentafluorophenyl)corrolate)(NO)]
  参考文献：
  名称：

  Iron complexes of tris(4-nitrophenyl)corrole, with emphasis on the (nitrosyl)iron complex

  摘要：

  我们制备了 5,10,15-三(4-硝基苯基)烯丙基醚的铁络合物，并利用各种光谱技术对其进行了表征。(亚硝基)铁络合物具有二磁性，其 X 射线结构显示出几乎完美的线性 Fe-N-O 键。利用 EPR 光谱和 15N 标记推断出了（亚硝基）铁珊瑚的单电子还原和氧化产物的氧化还原中心。

  DOI：

  10.1142/s1088424612500605

文献信息

• Substituent Effects on Nitrosyl Iron Corrole Complexes Fe(Ar₃C)(NO)
  作者：Crisjoe A. Joseph、Matthew S. Lee、Alexei V. Iretskii、Guang Wu、Peter C. Ford

  DOI：10.1021/ic051956j

  日期：2006.3.1

  Ford, P. C. J. Am. Chem. Soc. 2005, 127, 6737-6743), the second-order rate constants, k(NO), are all much faster ((1-9) x 10(8) M(-1) s(-1) at 298 K) than those for analogous iron(III) complexes of porphyrins. However, on a more microscopic level there is no obvious pattern in these rates with respect to the donor properties of the aryl ring substituents. The high reactivity of the ferric triarylcorrolates

  制备了一系列铁（III）Fe（Ar3C）（NO）在芳基上具有不同取代基的亚硝酰基三（5,10,15-芳基）-corrolate配合物，并比较了某些光谱和反应性能。各种Fe（Ar3C）（NO）配合物的循环伏安分析表明，相对于取代基的电子给体性质，单电子氧化电位和单电子还原电位均以系统且几乎相同的趋势响应。在亚硝酰基拉伸频率nu（NO）中观察到了类似的模式，该频率随较强的供体取代基而适度降低。Fe（Ar3C）（NO）溶液在甲苯中的快速光解会导致NO解离，然后迅速形成[瞬态]依赖的瞬态衰减（大概是Fe（Ar3C））以再生原始光谱。如在较早的对Fe（TNPC）（NO）（TNPC3- = 5,10,15-三（4-硝基-苯基）Corcorate）的快速光解研究中所见，Joseph，C.; Ford，PCJ Am.Chem.Soc （2005，127，6737-6743），二阶速率常数k（NO）在298
• Reversible Reactions of Nitric Oxide with a Binuclear Iron(III) Nitrophorin Mimic
  作者：Vinay K. Sharma、Azad Saini、Natalia Fridman、Harry B. Gray、Zeev Gross

  DOI：10.1002/chem.202302860

  日期：2024.1.11

  Strong attractive interactions between corrole subunits drive the release of nitric oxide from iron(III) nitrosyls, mimicking nitrophorin function.

  咔咯亚基之间的强吸引力相互作用驱动亚硝酰基铁 (III) 释放一氧化氮，模仿硝基蛋白的功能。
• β-Nitro Derivatives of Iron Corrolates
  作者：Sara Nardis、Manuela Stefanelli、Pruthviraj Mohite、Giuseppe Pomarico、Luca Tortora、Machima Manowong、Ping Chen、Karl M. Kadish、Frank R. Fronczek、Gregory T. McCandless、Kevin M. Smith、Roberto Paolesse

  DOI：10.1021/ic3002459

  日期：2012.3.19

  Two different methods for the regioselective nitration of different meso-triarylcorroles leading to the corresponding beta-substituted nitrocorrole iron complexes have been developed. A two-step procedure affords three Fe(III) nitrosyl products-the unsubstituted corrole, the 3-nitrocorrole, and the 3,17-dinitrocorrole. In contrast, a one-pot synthetic approach drives the reaction almost exclusively to formation of the iron nitrosyl 3,17-dinitrocorrole. Electron-releasing substituents on the meso-aryl groups of the triarylcorroles induce higher yields and longer reaction times than what is observed for the synthesis of similar triarylcorroles with electron-withdrawing functionalities, and these results can be confidently attributed to the facile formation and stabilization of an intermediate iron corrole pi-cation radical. Electron-withdrawing substituents on the meso-aryl groups of triarylcorrole also seem to labilize the axial nitrosyl group which, in the case of the pentafluorophenylcorrole derivative, results in the direct formation of a disubstituted iron mu-oxo dimer complex. The influence of meso-aryl substituents on the progress and products of the nitration reaction was investigated. In addition, to elucidate the most important factors which influence the redox reactivity of these different iron nitrosyl complexes, selected compounds were examined by cyclic voltammetry and thin-layer UV-visible or FTIR spectroelectrochemistry in CH2Cl2.