N-(4-methoxyphenyl)-N,N-di[9-(2-ethylhexyl)carbazol-3-yl]amine | 912654-88-7

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-(4-methoxyphenyl)-N,N-di[9-(2-ethylhexyl)carbazol-3-yl]amine
• 英文别名: 9-(2-ethylhexyl)-N-[9-(2-ethylhexyl)carbazol-3-yl]-N-(4-methoxyphenyl)carbazol-3-amine
• CAS: 912654-88-7
• 化学式: C₄₇H₅₅N₃O
• 分子量: 677.973
• InChiKey: HVMOGGWDWBKZMH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  14.1
• 重原子数：
  51
• 可旋转键数：
  16
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  22.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  N-(4-methoxyphenyl)-N,N-di[9-(2-ethylhexyl)carbazol-3-yl]amine 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 以1.16 g的产率得到N-(4-hydroxyphenyl)-N,N-di[9-(2-ethylhexyl)carbazol-3-yl]amine
  参考文献：
  名称：

  Di(9-alkylcarbazol-3-yl)arylamines as Electroactive Amorphous Materials for Optoelectronics

  摘要：

  Star-shaped molecules of di(9-alkylcarbazol-3-yl)arylamines were synthesized and found to constitute new glass-forming materials with glass transition temperatures ranging from 40 to 147 degrees C. The electron photoemission spectra of the molecular glasses were recorded and ionisation potentials of 4.9-5.0 eV were established. Room temperature time of flight hole drift mobilities of the di(9-alkylcarbazol-3-yl)phenylamines molecularly dispersed in polycarbonate-Z approached 5.10(-6) cm(2)/Vs at high electric fields. Some of the compounds were converted to cross-linkable derivatives, which are potential components for insoluble charge transport layers.

  DOI：

  10.1007/s00706-006-0509-x
• 作为产物：
  描述：

  3-iodo-9-(2-ethylhexyl)carbazole 、 甲氧苯胺 在 18-冠醚-6 、 铜 、 potassium carbonate 作用下， 以 邻二氯苯 为溶剂， 反应 20.0h， 以6 g的产率得到N-(4-methoxyphenyl)-N,N-di[9-(2-ethylhexyl)carbazol-3-yl]amine
  参考文献：
  名称：

  Di(9-alkylcarbazol-3-yl)arylamines as Electroactive Amorphous Materials for Optoelectronics

  摘要：

  Star-shaped molecules of di(9-alkylcarbazol-3-yl)arylamines were synthesized and found to constitute new glass-forming materials with glass transition temperatures ranging from 40 to 147 degrees C. The electron photoemission spectra of the molecular glasses were recorded and ionisation potentials of 4.9-5.0 eV were established. Room temperature time of flight hole drift mobilities of the di(9-alkylcarbazol-3-yl)phenylamines molecularly dispersed in polycarbonate-Z approached 5.10(-6) cm(2)/Vs at high electric fields. Some of the compounds were converted to cross-linkable derivatives, which are potential components for insoluble charge transport layers.

  DOI：

  10.1007/s00706-006-0509-x

文献信息

• Di(9-alkylcarbazol-3-yl)arylamines as Electroactive Amorphous Materials for Optoelectronics
  作者：Vida Peciuraite、Violeta Vaitkeviciene、Saulius Grigalevicius、Juozas V. Grazulevicius、Vygintas Jankauskas

  DOI：10.1007/s00706-006-0509-x

  日期：2006.8

  Star-shaped molecules of di(9-alkylcarbazol-3-yl)arylamines were synthesized and found to constitute new glass-forming materials with glass transition temperatures ranging from 40 to 147 degrees C. The electron photoemission spectra of the molecular glasses were recorded and ionisation potentials of 4.9-5.0 eV were established. Room temperature time of flight hole drift mobilities of the di(9-alkylcarbazol-3-yl)phenylamines molecularly dispersed in polycarbonate-Z approached 5.10(-6) cm(2)/Vs at high electric fields. Some of the compounds were converted to cross-linkable derivatives, which are potential components for insoluble charge transport layers.