K[PtCl₃S(O)Me(p-C₆H₄Me)] | 127157-15-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: K[PtCl₃S(O)Me(p-C₆H₄Me)]
• 英文别名: K[PtCl3(methyl-p-tolylsulfoxide)]；potassium trichloro{(-)-methyl p-tolyl sulfoxide}platinate (II)；potassium (-)-trichloro[S-methyl p-tolyl sulfoxide]platinate(II)；[Pt(p-MeC6H4SOCH3)Cl3]
• CAS: 127157-15-7
• 化学式: C₈H₁₀Cl₃OPtS*K
• 分子量: 494.77
• InChiKey: XXDFLXPPXCZMLZ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  0.8
• 重原子数：
  15.0
• 可旋转键数：
  2.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  17.07
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  吡啶 、 K[PtCl₃S(O)Me(p-C₆H₄Me)] 以 水 为溶剂， 以88.6%的产率得到cis-(methyl p-tolyl sulfoxide pyridine platinum(II) chloride complex)
  参考文献：
  名称：

  摘要：

  The reactions of the optically active geometric isomers of the platinum(II) complex (-)-[Pt(Me-p-TolSO)(Py)Cl-2] with several nucleophilic reagents (Py, Ph3PS, Ph3P, Ph3As, and Me2SO) were studied by optical rotatory dispersion, IR spectroscopy, and H-1 and P-31 NMR spectroscopy. A mechanism for the reaction is proposed.

  DOI：

  10.1023/a:1011357929566
• 作为产物：
  描述：

  (S)-(-)-甲基对甲苯亚砜 、 potassium tetrachloroplatinate(II) 以 水 为溶剂， 以80%的产率得到K[PtCl₃S(O)Me(p-C₆H₄Me)]
  参考文献：
  名称：

  Trofimov, A. E.; Lobadyuk, V. I.; Skvortsov, N. K., Journal of general chemistry of the USSR, 1989, vol. 59, p. 2493 - 2494

  摘要：

  DOI：

文献信息

• 2-Pyridylmetallocenes, part IV. Cycloplatination of 2-pyridyl-ferrocene, -ruthenocene and –cymantrene. Molecular structures of σ-Pt{CpM[C5H3(2-C5H4N)]}Cl (DMSO) (M=Fe, Ru) and σ-Pt{CpFe[C5H3(2-C5H4N)]}(acac)
  作者：Karlheinz Sünkel、Ramona Branzan、Stefan Weigand

  DOI：10.1016/j.ica.2013.01.022

  日期：2013.4

  RuCp, Mn(CO)3, R = H, CH3) react with cis-[PtCl2(DMSO)2] to give the cycloplatinated complexes σ-PtLnM[C5H2(2-C5H4N)(R)]}Cl (DMSO) (MLn = FeCp (R = H: 2a; R = Me: 2b), RuCp (R = H, 3a; R = Me, 3b), Mn(CO)3 (R = H, 4)). The reaction of 1a with the chiral sulfoxide complexes cis-[PtCl2S(O)Me(p-C6H4Me)}2] or K[PtCl3S(O)Me(p-C6H4Me)] yields a mixture of σ-PtCpFe[C5H2(2-C5H4N)(R)]}Cl[S(O)Me(p-C6H4Me)]

  2-吡啶基茂金属[C 5 H 3 R（2-C 5 H 4 N）] ML n（1a – e，ML n  = FeCp，RuCp，Mn（CO）3，R = H，CH 3）与顺式反应- [PtCl 2（DMSO）2 ]得到环铂配合物σ-PtL n M [C 5 H 2（2-C 5 H 4 N）（R）]} Cl（DMSO）（ML n  = FeCp（ R = H：2a ; R = Me：2b），RuCp（R = H，3a ; R = Me，3b），Mn（CO）3（R = H，4））。的反应1A与手性亚砜配合物的顺式- [氯铂酸2 S（O）Me（p -C 6 H ^ 4 Me）的} 2 ]或K [氯铂酸3 S（O）我（p -C 6 H ^ 4我）]产生σ-PtCpFe [C 5 H 2（2-C 5 H 4 N）（R）]} Cl [S（O）Me（p -C 6 H 4 Me）]非对映异构体（R p R
• Enantiomeric discrimination in coordination of sulfoxides to platinum(II): X-ray structure of the kinetically over thermodynamically favoured erythro cis-dichloro-bis(methyl-p-tolylsulfoxide)platinum(II)
  作者：Francesco Paolo Fanizzi、Giovanni Natile、Maurizio Lanfranchi、Antonio Tiripicchio

  DOI：10.1016/s0020-1693(97)05586-2

  日期：1997.11

  The erythro bis-sulfoxide complex cis-[PtCl2R-S(O)MeTol(p)}S-S(O)MeTol(p)}] has been isolated, as the kinetically preferred product, in the reaction of K2PtCl4 with methyl-p-tolylsulfoxide in water/methanol. The crystal and molecular structure of the title complex has been determined by X-ray diffraction methods and compared with those of the thermodynamically preferred three species cis-[PtCl2S(O)R'R ''}(2)] (R' = Me, R '' = Ph or Tol(p)). Crystal data: monoclinic, space group P2(1)/n, a = 19.081(3), b = 5.992(1), c = 19.398(3) Angstrom, beta = 119.05(2)degrees, Z = 4, R = 0.0355. The kinetics of isomerization in chloroform of the erythro cis-[PtCl2S(O)MeTol(p)}(2)] to a 1:3 mixture of erythro and threo species has been investigated. (C) 1997 Elsevier Science S.A.
• Spevak; Lobadyuk; Skvortsov, Russian Journal of General Chemistry, 1999, vol. 69, # 5, p. 715 - 720
  作者：Spevak、Lobadyuk、Skvortsov、Konovalov、Bel'skii、Skvortsov

  DOI：——

  日期：——