[Zn(2-aminomethylaniline)2(NO3)2] | 1253590-75-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Zn(2-aminomethylaniline)2(NO3)2]
• CAS: 1253590-75-8
• 化学式: C₁₄H₂₀N₆O₆Zn
• 分子量: 433.739
• InChiKey: YZOLNCNPRSIXIQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 2-氨基苄胺 以 甲醇 为溶剂， 以80%的产率得到[Zn(2-aminomethylaniline)2(NO3)2]
  参考文献：
  名称：

  N-donor ligand complexes of nickel, zinc and copper: Comparisons with tetradentate N-donor ligands derived from Schiff bases

  摘要：

  The nickel and zinc complexes of 2-aminomethylaniline (AMA) are reported. Both metals form the octahedral complex [M(AMA)(2)(ONO2)(2)] (M = Ni, Zn) where the aromatic ligands lie in the meridial plane with the anilino donors trans to one another. The remaining nitrates coordinate axially. A simple comparison with the nitrogen donor disposition (cis/trans) in nickel complexes of tetradentate N-4 donor ligands derived from symmetric Schiff base ligands is presented. The discussion is extended to interrogate the bonding motifs of the nitrate ligands viz -ONO2 in the nickel complexes of AMA compared to the two motifs (viz O2NO and ONO2) that are isolated for the nickel complexes of the macrocycle hexamethyltetraazacyclotetradecane. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.06.001