dibutylbis(phenylacetato)tin(IV) | 132712-68-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: dibutylbis(phenylacetato)tin(IV)
• 英文别名: Dibutyltin(2+);2-phenylacetate
• CAS: 132712-68-6
• 化学式: C₂₄H₃₂O₄Sn
• 分子量: 503.226
• InChiKey: PVIGIYHSKGOZSU-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  dibutylbis(phenylacetato)tin(IV) hydrate 以 neat (no solvent) 为溶剂， 生成 dibutylbis(phenylacetato)tin(IV)
  参考文献：
  名称：

  Crystal structure of trans-C2SnO5 pentagonal bipyramidal dibutylbis(phenylacetato)tin(IV) hydrate

  摘要：

  The Lewis acidity of tin in a diorganotin is dicarboxylate is demonstrated in this first example of a 1/1 adduct of the ester with a neutral ligand. The structure of dibutyltin bisphenylacetate hydrate [(C4H9)2Sn(O2CCH2C6H5)2 . H2O] has been determined from 1211 \F0\ greater-than-or-equal-to 6 sigma\F\ Mo K-alpha reflections and refined to an R(F) of 0.061 [space group P2/a with a = 8.416(2), b = 10.391(5), c = 14.28(1) angstrom, beta = 98.42(4) degrees and Z = 2]. The C alpha atoms [Sn-C 2.101(8) angstrom; C-Sn-C 169.9(5)-degrees] make up the apices and the O(carboxylate) [Sn-O 2.234(5), 2.439(7) angstrom; O-Sn-O 55.7(2)-degrees] and O(water) [Sn-O 2.342(8) angstrom] atoms the equatorial points of the trans-C2SnO5 pentagonal bipyramid around the Sn atom. The molecular symmetry is C2, and the Sn and O(water) atoms lie along a crystallographic twofold axis. The aqua ligand forms donor H-bonds with neighboring carboxylato groups to link the molecules into a double zigzag chain running parallel to alpha.

  DOI：

  10.1007/bf01158972