[Pt((C2H5)2NCHCHCH2)(2-(2',6'-dimethylphenylazo)-4-methylphenolato)] | 918824-82-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Pt((C2H5)2NCHCHCH2)(2-(2',6'-dimethylphenylazo)-4-methylphenolato)]
• CAS: 918824-82-5
• 化学式: C₂₂H₂₉N₃OPt
• 分子量: 546.572
• InChiKey: LRFYCGXKUNHNHW-WJACTTGFSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 potassium tetrachloroplatinate(II) 、 2-hydroxy-5,2',6'-trimethylazobenzene 、 三乙胺 以 甲醇 为溶剂， 以40%的产率得到[Pt((C2H5)2NCHCHCH2)(2-(2',6'-dimethylphenylazo)-4-methylphenolato)]
  参考文献：
  名称：

  Unusual Transformation of Trialkylamines Mediated by Platinum

  摘要：

  An interesting chemical transformation of trialkylamines has taken place during the reaction of 2-(2', 6'-dimethylphenylazo)- 4-methylphenol ( 1) with K-2[ PtCl4] in refluxing methanol in the presence of trialkylamines, leading to the formation of organoplatinum complexes ( 2 and 3), where ligand 1 is coordinated as a bidentate N, O donor and the transformed trialkylamines are coordinated as bidentate C, N donors.

  DOI：

  10.1021/om0607494