Bis-isobutyl-phosphinsulfid | 691-95-2

• 分子结构分类: 有机化合物 - 有机硫化合物
• 英文名称: Bis-isobutyl-phosphinsulfid
• 英文别名: Diisobutyl-phosphin-sulfid
• CAS: 691-95-2
• 化学式: C₈H₁₉PS
• 分子量: 178.279
• InChiKey: QIAFBLQXRRLYBP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.97
• 重原子数：
  10.0
• 可旋转键数：
  4.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  1-十二烯十二碳烯α-十二碳烯α-十二碳烯 、 Bis-isobutyl-phosphinsulfid 在 偶氮二异丁腈 作用下， 生成 Di-isobutyl-n-dodecylphosphinsulfid
  参考文献：
  名称：

  二十五磷化磷与有机磷化硫

  摘要：

  准备秒的两个新过程。描述了分别涉及二烷基氨基-二烷基或二芳基膦与硫化氢和（RO）2 P（S）H的二烷基硫代膦酸酯与GRIGNARD或有机锂试剂反应的硫化膦。秒的加法。膦硫化物与烯烃的缩合反应。报道了具有N-羟甲基二烷基胺的硫化膦。叔的转换。磷化氢硫化物相应的叔。用过氧化氢很容易获得氧化膦。几种新的不对称叔叔的物理性质。列出了硫化膦和氧化物。

  DOI：

  10.1002/hlca.19660490406
• 作为产物：
  描述：

  二异丁基膦 在 sulfur 作用下， 生成 Bis-isobutyl-phosphinsulfid
  参考文献：
  名称：

  SECONDARY PHOSPHINE SULFIDES

  摘要：

  DOI：

  10.1021/ja01502a082

文献信息

• Coated semiconductor nanocrystals and products including same
  申请人：SAMSUNG ELECTRONICS CO., LTD.

  公开号：US10008631B2

  公开（公告）日：2018-06-26

  A coated quantum dot is provided wherein the quantum dot is characterized by having a solid state photoluminescence external quantum efficiency at a temperature of 90° C. or above that is at least 95% of the solid state photoluminescence external quantum efficiency of the semiconductor nanocrystal at 25° C. Products including quantum dots described herein are also disclosed.

  提供了一种涂层量子点，其中量子点的特征是在 90°C 或以上温度下具有固态光致发光外部量子效率，该效率至少是半导体纳米晶体在 25°C 下固态光致发光外部量子效率的 95%。
• Methods for coating semiconductor nanocrystals
  申请人：SAMSUNG ELECTRONICS CO., LTD

  公开号：US10096678B2

  公开（公告）日：2018-10-09

  A coated quantum dot and methods of making coated quantum dots are provided.

  提供了一种涂层量子点和制作涂层量子点的方法。
• METHOD OF MAKING SEMICONDUCTOR NANOCRYSTALS
  申请人：QD VISION, INC.

  公开号：US20140312286A1

  公开（公告）日：2014-10-23

  A method for preparing semiconductor nanocrystals includes reacting one or more semiconductor nanocrystal precursors in a liquid medium in the presence of a boronic compound at a reaction temperature resulting in semiconductor nanocrystals. Semiconductor nanocrystals are also disclosed.
• SEMICONDUCTOR NANOCRYSTALS, A METHOD FOR COATING SEMICONDUCTOR NANOCRYSTALS, AND PRODUCTS INCLUDING SAME
  申请人：QD VISION, INC.

  公开号：US20140284549A1

  公开（公告）日：2014-09-25

  A semiconductor nanocrystal that emits green light having a peak emission with a full width at half maximum of about 30 nm or less at 100° C. and a method of making coated semiconductor nanocrystals are provided. Materials and other products including semiconductor nanocrystals described herein and materials and other products including semiconductor nanocrystals prepared by a method described herein are also disclosed.
• METHODS FOR COATING SEMICONDUCTOR NANOCRYSTALS
  申请人：QD VISION, INC.

  公开号：US20150021551A1

  公开（公告）日：2015-01-22

  A coated quantum dot and methods of making coated quantum dots are provided. Products including quantum dots described herein are also disclosed.