(E)-2-lithio-1-(2-lithiophenyl)-1-phenylpent-1-ene | 132905-00-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (E)-2-lithio-1-(2-lithiophenyl)-1-phenylpent-1-ene
• CAS: 132905-00-1；142576-68-9
• 化学式: C₁₇H₁₆Li₂
• 分子量: 234.196
• InChiKey: JLTFPCROBSECEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.76
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  (diphenylmethylene)cyclobutane 在 lithium 作用下， 以 乙醚 为溶剂， 反应 25.0h， 生成 (E)-2-lithio-1-(2-lithiophenyl)-1-phenylpent-1-ene
  参考文献：
  名称：

  Polylithiumorganische verbindungen

  摘要：

  Diphenylmethylenecyclobutane (5) in diethyl ether reacts smoothly at room temperature with lithium powder, whereby a cyclobutane segma-bond is reductively cleaved. The 1,4-dilithio compound 7 which is formed primarily, however, slowly undergoes rearrangement with 1,7-proton shift yielding another, presumably double-bridged 1,4-dilithio compound 8, which is rather stable in diethyl ether.

  DOI：

  10.1016/0022-328x(91)86211-8

文献信息

• Polylithiumorganische verbindungen
  作者：Adalbert Maercker、Klaus-Dieter Klein

  DOI：10.1016/0022-328x(91)86211-8

  日期：1991.1

  Diphenylmethylenecyclobutane (5) in diethyl ether reacts smoothly at room temperature with lithium powder, whereby a cyclobutane segma-bond is reductively cleaved. The 1,4-dilithio compound 7 which is formed primarily, however, slowly undergoes rearrangement with 1,7-proton shift yielding another, presumably double-bridged 1,4-dilithio compound 8, which is rather stable in diethyl ether.