An ocular lens material made of a copolymer of monomers respectively represented by formula (I), (II) and (III), which has a well-balanced combination of mechanical strength, flexibility, oxygen permeability, shape stability, transparency, and hydrophilicity.
[In the formula, R1 and R2 each represents H or CH3; R3 to R8 each represents a C1-10 monovalent hydrocarbon group optionally substituted with fluorine atom(F); A1 and A2 each represents -O-, -S-, or -NR9- (wherein R9 represents H or a C1-10 monovalent hydrocarbon group optionally substituted with F); X1 and X2 each represents a single bond or a divalent organic group; m is 0 to 300; R10 represents H or CH3; A3 represents -O-, -S-, or -NR11-(wherein R11 represents H, or a C1-10 monovalent hydrocarbon group optionally substituted with F); Y represents a monocyclic monovalent hydrocarbon group; R12 represents H or CH3; A4 represents -O-, -S-, or -NR13- (wherein R13 represents H or a C1-10 monovalent hydrocarbon group optionally substituted with F); X3 represents a single bond or a divalent organic group; Z1 to Z5 each represents either a C1-10 monovalent hydrocarbon group optionally substituted with F or -OR14 [wherein R14 represents either a C1-10 monovalent hydrocarbon group optionally substituted with F or a group represented by -O-SiR15R16R17 wherein R15 to R17 each represents either a C1-10 monovalent hydrocarbon group optionally substituted with F or -O-R18 (wherein R18 represents a C1-10 monovalent hydrocarbon group optionally substituted with F)}]; and n is 0 to 300.]
一种由分别由式(I)、(II)和(III)表示的单体共聚物制成的眼透镜材料,它在机械强度、柔韧性、透氧性、形状稳定性、透明度和亲
水性方面具有良好的平衡组合。
[式中,R1 和 R2 分别代表 H 或
CH3;R3 至 R8 分别代表任选被
氟原子(F)取代的 C1-10 单价烃基;A1 和 A2 分别代表 -O-、-S- 或 -NR9-(其中 R9 代表 H 或任选被 F 取代的 C1-10 单价烃基);X1 和 X2 各自代表单键或二价有机基团;m 为 0 至 300;R10 代表 H 或 ;A3 代表 -O-、-S- 或 -NR11-(其中 R11 代表 H 或任选被 F 取代的 C1-10 单价烃基);Y 代表单环单价烃基;R12 代表 H 或 ;A4 代表-O-、-S-或-NR13-(其中 R13 代表 H 或任选被 F 取代的 C1-10 单价烃基); X3 代表单键或二价有机基团;Z1至Z5各自代表任选被F取代的C1-10一价烃基或-OR14[其中R14代表任选被F取代的C1-10一价烃基或由-O-SiR15R16R17代表的基团其中R15至R17各自代表任选被F取代的C1-10一价烃基或-O-R18(其中R18代表任选被F取代的C1-10一价烃基}];以及n为0至300。]