Phenyl-(2,4,6-trimethylbenzoyl)thiophosphinic S-(4-methylphenyl) ester | 352706-96-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenyl-(2,4,6-trimethylbenzoyl)thiophosphinic S-(4-methylphenyl) ester
• 英文别名: [(4-Methylphenyl)sulfanyl-phenylphosphoryl]-(2,4,6-trimethylphenyl)methanone
• CAS: 352706-96-8
• 化学式: C₂₃H₂₃O₂PS
• 分子量: 394.474
• InChiKey: BDGNPKSZNLQNKZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  27
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  59.4
• 氢给体数：
  0
• 氢受体数：
  3

文献信息

• Organometallic monoacylarylphosphines
  申请人：——

  公开号：US20010031898A1

  公开（公告）日：2001-10-18

  1 R 1 and R 2 independently of one another are C 1 -C 20 alkyl, OR 11 , CF 3 or halogen; R 3 , R 4 and R 5 independently of one another are hydrogen, C-C 20 alkyl, OR 11 or halogen; R 6 , R 7 , R 8 , R 9 and R 10 independently of one another are hydrogen, C 1 -C 20 alkyl; C 2 -C 20 alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substituted by OH and/or SH; or R 6 , R 7 , R 8 , R 9 and R 10 are OR 11 , SR 11 , N(R 12 )(R 13 ), phenyl or halogen; R 11 is C 1 -C 20 alkyl, C 3 -C 8 cycloalkyl, phenyl, benzyl or C 2 -C 20 alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; R 12 and R 13 independently of one another are hydrogen, C 1 -C 20 alkyl, C 3 -C 8 cycloalkyl, phenyl, benzyl or C 2 -C 20 alkyl which is interrupted once or more than once by nonconsecutive O atoms and which is unsubstituted or substituted by OH and/or SH; or R 12 and R 13 together are C 3 -C 5 alkylene which can be interrupted by O, S or NR 14 ; R 14 is hydrogen, phenyl, C 1 -C 12 alkyl or C 2 -C 12 alkyl which is interrupted once or more than once by O or S and which is unsubstituted or substituted by OH and/or SH; and M is hydrogen, Li, Na or K; are valuable intermediates for the preparation of unsymmetrical bisacylphosphine oxides and monoacylphosphine oxides.

  翻译结果： 独立于彼此的R1和R2是C1-C20烷基，OR11，CF3或卤素；R3、R4和R5独立于彼此是氢、C-C20烷基，OR11或卤素；R6、R7、R8、R9和R10独立于彼此是氢、C1-C20烷基；C2-C20烷基在非连续的O原子处中断一次或多次，未经取代或由OH和/或SH取代；或者R6、R7、R8、R9和R10是OR11、SR11、N（R12）（R13）、苯基或卤素；R11是C1-C20烷基、C3-C8环烷基、苯基、苄基或由O或S中断一次或多次的C2-C20烷基，未经取代或由OH和/或SH取代；R12和R13独立于彼此是氢、C1-C20烷基、C3-C8环烷基、苯基、苄基或在非连续的O原子处中断一次或多次的C2-C20烷基，未经取代或由OH和/或SH取代；或者R12和R13一起是C3-C5脂肪烃，可以由O、S或NR14中断；R14是氢、苯基、C1-C12烷基或由O或S中断一次或多次的C2-C12烷基，未经取代或由OH和/或SH取代；M是氢、Li、Na或K；它们是制备非对称双酰基膦氧化物和单酰基膦氧化物的有价值的中间体。
• US6399805B2
  申请人：——

  公开号：US6399805B2

  公开（公告）日：2002-06-04
• US6579663B2
  申请人：——

  公开号：US6579663B2

  公开（公告）日：2003-06-17