6-[(naphthalen-2-ylamino)methylidene]cyclohexa-2,4-dien-1-one | 1689-72-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 6-[(naphthalen-2-ylamino)methylidene]cyclohexa-2,4-dien-1-one
• 英文别名: o-Hydroxybenzylidene-2-naphthylamine
• CAS: 1689-72-1
• 化学式: C₁₇H₁₃NO
• 分子量: 247.296
• InChiKey: FLUBOKFZUHGTFP-LDADJPATSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  19.0
• 可旋转键数：
  2.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  32.59
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  6-[(naphthalen-2-ylamino)methylidene]cyclohexa-2,4-dien-1-one 在 sodium tetrahydroborate 作用下， 以 乙醇 为溶剂， 生成 N-2(hydroxybenzyl)-β-naphthylamine
  参考文献：
  名称：

  Synthesis of Metal Complexes Chelated with N-Naphthalenyl Aminomethyl Phenol and Their Application to OELD

  摘要：

  The metal complexes chelated with N-naphthalenyl aminomethyl phenol were synthesized and the beryllium complex was applied to the organic electroluminescent devices as a blue light-emitting layer. Emission wavelength was observed at 406 nm in luminescence spectra for this complex. Its ionization potential (IP), electron affinity (EA) and band gap were investigated with cyclic voltammetry and found to be consistent with their UV-vis absoption spectral data.

  DOI：

  10.1080/10587250108030038
• 作为产物：
  描述：

  邻甲基苄醇 、 2-萘胺 以 乙醚 为溶剂， 生成 6-[(naphthalen-2-ylamino)methylidene]cyclohexa-2,4-dien-1-one
  参考文献：
  名称：

  Synthesis of Metal Complexes Chelated with N-Naphthalenyl Aminomethyl Phenol and Their Application to OELD

  摘要：

  The metal complexes chelated with N-naphthalenyl aminomethyl phenol were synthesized and the beryllium complex was applied to the organic electroluminescent devices as a blue light-emitting layer. Emission wavelength was observed at 406 nm in luminescence spectra for this complex. Its ionization potential (IP), electron affinity (EA) and band gap were investigated with cyclic voltammetry and found to be consistent with their UV-vis absoption spectral data.

  DOI：

  10.1080/10587250108030038

文献信息

• CATALYST COMPONENT FOR PROPYLENE POLYMERIZATION, PREPARATION METHOD THEREFOR AND CATALYST HAVING SAME
  申请人：China Petroleum&Chemical Corporation

  公开号：EP3135699A1

  公开（公告）日：2017-03-01

  The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compouns as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity. The obtained polymer has not only a wider molecular weight distribution, but also a high melt index and isotacticity.

  本发明公开了一种用于丙烯聚合的催化剂组分，由钛、镁、卤素和内部电子供体 A 组成，其中所述内部电子供体 A 选自如式 I 所示的化合物、 在式 I 中，R 选自氢、羟基和取代或未取代的 C1-C30 碳氢基，优选选自氢、羟基和取代或未取代的 C1-C20 烷基、C6-C30 芳基、C6-C30 杂芳基、C7-C30 烷芳基和 C7-C30 芳烷基；R1和R2可以彼此相同或不同，并且选自氢和取代或未取代的C1-C30烃基，优选选自氢和取代或未取代的C1-C20烷基、C6-C30芳基、C7-C30烷芳基和C7-C30芳烷基。根据本发明，使用如式 I 所示的化合物作为丙烯聚合的内部电子供体化合物，催化剂具有更高的活性，并且活性延迟的速度较慢。所得到的聚合物不仅分子量分布更广，而且熔融指数和等活度都很高。
• Catalyst component for propene polymerization, preparation method thereof, and catalyst containing the same
  申请人：China Petroleum & Chemical Corporation

  公开号：US10184017B2

  公开（公告）日：2019-01-22

  The present invention discloses a catalyst component for propene polymerization, comprising titanium, magnesium, halogen, and internal electron donor A, wherein said internal electron donor A is selected from the compounds as shown in Formula I, in Formula I, R is selected from hydrogen, hydroxyl, and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen, hydroxyl, and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C6-C30 heteroaryl, C7-C30 alkylaryl and C7-C30 arylalkyl; R1 and R2 may be identical to or different from each other, and are selected from hydrogen and substituted or unsubstituted C1-C30 hydrocarbyl, preferably from hydrogen and substituted or unsubstituted C1-C20 alkyl, C6-C30 aryl, C7-C30 alkylaryl and C7-C30 arylalkyl. According to the present invention, by using the compound as shown in Formula I as internal electron donor compound for propene polymerization, the catalyst has a higher activity, and a slow rate of delay of activity. The obtained polymer has not only a wider molecular weight distribution, but also a high melt index and isotacticity.

  本发明公开了一种用于丙烯聚合的催化剂组分，由钛、镁、卤素和内部电子供体 A 组成，其中所述内部电子供体 A 选自如式 I 所示的化合物、 在式 I 中，R 选自氢、羟基和取代或未取代的 C1-C30 碳氢基，优选选自氢、羟基和取代或未取代的 C1-C20 烷基、C6-C30 芳基、C6-C30 杂芳基、C7-C30 烷芳基和 C7-C30 芳烷基；R1和R2可以彼此相同或不同，并且选自氢和取代或未取代的C1-C30烃基，优选选自氢和取代或未取代的C1-C20烷基、C6-C30芳基、C7-C30烷芳基和C7-C30芳烷基。根据本发明，使用如式 I 所示的化合物作为丙烯聚合的内部电子供体化合物，催化剂具有更高的活性，并且活性延迟的速度较慢。所得到的聚合物不仅分子量分布更广，而且熔融指数和等活度都很高。
• Kozlov; Sauts; Gusak, Russian Journal of Organic Chemistry, 2000, vol. 36, # 4, p. 531 - 538
  作者：Kozlov、Sauts、Gusak

  DOI：——

  日期：——
• Synthesis and spectral properties of coumaronyl-substituted benzo[f]quinolines
  作者：N. G. Kozlov、K. N. Gusak、S. A. Makhnach

  DOI：10.1007/bf01165728

  日期：1996.7
• KOZLOV N. S.; GLADCHENKO L. F.; KOROTYSHOVA G. P., XIMIYA GETEROTSIKL. SOED., 1980, HO 7, 976-979
  作者：KOZLOV N. S.、 GLADCHENKO L. F.、 KOROTYSHOVA G. P.

  DOI：——

  日期：——