[(C6F5)2Pt(μ-PPh2)2Pd(NCCH3)2] | 881073-96-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(C6F5)2Pt(μ-PPh2)2Pd(NCCH3)2]
• CAS: 881073-96-7
• 化学式: C₄₀H₂₆F₁₀N₂P₂PdPt
• 分子量: 1088.09
• InChiKey: IDDKEAGRZYKZTO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  [(C6F5)2Pt(μ-PPh2)2Pd(NCCH3)2] 以 二氯甲烷 为溶剂， 以27%的产率得到[Pt2Pd2(μ-PPh2)3(C6F5)3(PPh2C6F5)]
  参考文献：
  名称：

  An organometallic tetranuclear cluster with phosphine and phosphido ligands in nonclassical bonding modes: X-ray structural characterization

  摘要：

  The elimination of the NCMe ligand in [(C6F5)(2)Pt(mu-PPh2)(2)M(NCCH3)(2)] (M = Pd, Pt) results in the formation of the tetranuclear clusters [Pt2Pd2(p-PPh2)(3)(C6F5)(3)(PPh2C6F5)]1 and [Pt-4(mu-PPh2)(4)(C6F5)(4)](2). The structure of 1 indicates that one of the palladium centres is connected to the rest of the centres through two M-M bonds and two weaker eta(2) -C6H5 and eta(2) -P-C interactions. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.11.018
• 作为产物：
  描述：

  (NBu4)2{(pentafluorophenyl)2platinum(II)(μ-diphenylphosphido)2palladium(II)(pentafluorophenyl)2} 、 乙腈 在 HClO₄ 作用下， 以 甲醇 、 乙腈 为溶剂， 以76%的产率得到[(C6F5)2Pt(μ-PPh2)2Pd(NCCH3)2]
  参考文献：
  名称：

  Formation of PPh₂C₆F₅ through Phosphido Platinum and/or Palladium(III) Intermediates^,

  摘要：

  The two-electron oxidation reactions of the neutral [(C6F5)(2)M(mu-PR2)(2)M'(NCCH3)(2)] (M = M' = Pt or Pd, M = Pt, M' = Pd) complexes using I-2 as oxidant have been investigated by experimental (R = Ph) and electronic structure calculation methods (R = H). It was found that a reductive coupling of PR, and C6F5 takes place along the reaction pathway for all oxidized complexes. The most salient structural features of the [(C6F5)(2)Pt(mu-PR2)(2)Pd(C6F5)(2)](2-), [(C6F5)(2)Pd(mu-PR2)(2)Pd(acac)](-), and [(C6F5)(2)Pt(mu-PR2)(2)PtI2] complexes (experimental R = Ph) are reproduced very well by the B3LYP/lan12dz calculations (R = H).

  DOI：

  10.1021/om0508029